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US 4,731,418 AGranted
Diels-Alder graft polymers
AssigneeArco Chemical Company
InventorBarry D. Dean
Life of this patent
Estimating the term…
Abstract
Graft polymers between glassy polymers and elastomeric polymers prepared using Diels-Alder chemistry are disclosed.
Claims15
A graft polymer represented by formula (I):
- ##STR11## wherein R represents hydrogen or alkyl;
- R.sup.1 represents phenyl, alkyl substituted phenyl, chloro or bromo substituted phenyl, CO.sub.2 H, CO.sub.2 CH.sub.3, CO.sub.2 CH.sub.2 CH.sub.3, or C.tbd.N;
- X represents O, NH, NCH.sub.3, NCH.sub.2 CH.sub.3, NC(CH.sub.3).sub.3, NC.sub.6 H.sub.5, N-(p-Br)C.sub.6 H.sub.4, N-(p-CH.sub.3)C.sub.6 H.sub.4, N-[p-C(CH.sub.3).sub.3 ]C.sub.6 H.sub.4, or N-(p-CH.sub.3 O)C.sub.6 H.sub.4 ;
- the mole percent of the total recurring units designated by subscripts a+b+d equals 100 with a being a number from about 95 to about 99.5, b being a number from about 0.5 to about 5, and d being a number from 0 to about 45, with the proviso that if the recurring unit designated by subscript d is present, it is directly substituted for the recurring unit designated by the subscript a;
- the mole percent of the total recurring units designated by subscripts w+y+z equals 100, with w being a number from about 30 to about 55, y being a number from about 44.9 to about 55, and z being a number of from about 0.1 to about 15;
- and, wherein at least 1 percent of the recurring units designated by the subscript b and at least 1 percent of the recurring units designated by the subscript z have been reacted to form a graft structure.
3 more elements
A graft polymer represented by formula (II):
- ##STR12## wherein:
- R represents hydrogen or alkyl;
- R.sup.1 represents phenyl, alkyl substituted phenyl, chloro or bromo substituted phenyl, CO.sub.2 H, CO.sub.2 CH.sub.3, CO.sub.2 CH.sub.2 CH.sub.3, or C.tbd.N;
- X represents O, NH, NCH.sub.3, NCH.sub.2 CH.sub.3, NC(CH.sub.3).sub.3, NC.sub.6 H.sub.5, N-(p-Br)C.sub.6 H.sub.4, N-(p-CH.sub.3)C.sub.6 H.sub.4, N-[p-C(CH.sub.3).sub.3 ]C.sub.6 H.sub.4, or N-(p-CH.sub.3 O)C.sub.6 H.sub.4 ;
- the mole percent of the total recurring units designated by subscripts a+b+d equals 100 with a being a number from about 95 to about 99.5, b being a number from about 0.5 to about 5, and d being a number from 0 to about 45, with the proviso that if the recurring unit designated by subscript d is present, it is directly substituted for the recurring unit designated by the subscript a;
- the mole percent of the total recurring units designated by subscripts w+y+z equals 100, with w being a number from about 30 to about 55, y being a number from about 44.9 to about 55, and z being a number of from about 0.1 to about 15;
- and wherein at least 1 percent of the recurring units designated by the subscript b and at least 1 percent of the recurring units designated by the subscript z have been reacted to form a graft structure.
4 more elements
A graft polymer represented by formula (III):
- ##STR13## wherein:
- R represents hydrogen or alkyl;
- R.sup.1 represents phenyl, alkyl substituted phenyl, chloro or bromo substituted phenyl, CO.sub.2 H, CO.sub.2 CH.sub.3, CO.sub.2 CH.sub.2 CH.sub.3, or C.tbd.N;
- X represents O, NH, NCH.sub.3, NCH.sub.2 CH.sub.3, NC(CH.sub.3).sub.3, NC.sub.6 H.sub.5, N-(p-Br)C.sub.6 H.sub.4, N-(p-CH.sub.3)C.sub.6 H.sub.4, N-[p-C(CH.sub.3).sub.3 ]C.sub.6 H.sub.4, or N-(p-CH.sub.3 O)C.sub.6 H.sub.4 ;
- the mole percent of the total recurring units designated by subscripts a+b+d equals 100 with a being a number from about 95 to about 99.5, b being a number from about 0.5 to about 5, and d being a number from 0 to about 45, with the proviso that if the recurring unit designated by subscript d is present, it is directly substituted for the recurring unit designated by the subscript a;
- the mole percent of the total recurring units designated by subscripts w+y+z equals 100, with w being a number from about 30 to about 55, y being a number from about 44.9 to about 55, and z being a number of from about 0.1 to about 15;
- and wherein at least 1 percent of the recurring units designated by the subscript b and at least 1 percent of the recurring units designated by the subscript z have been reacted to form a graft structure.
4 more elements
Dependencies are inferred from the claim text.