Lubricants for halogen-containing thermoplastic resins and compositions prepared therefrom
AssigneeMorton Thiokol, Inc.
InventorsKarl R. Wursthorn, Jeffrey R. Hyde, Miller H. Goose, Jr.
Life of this patent
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Abstract
Lubricants used in forming halogen-containing thermoplastic resin compositions are addition products of mercaptans and olefins and contain at least one free carboxyl group. Of particular interest are addition products of thio carboxylic acids and long chain alpha-olefins. These lubricants are used in amounts of from about 0.05 to about 5 parts per 100 parts of thermoplastic resin composition.
Claims12
A thermoplastic resin composition comprising a halogen-containing thermoplastic resin and a lubricant compound which is an addition product of (1) an olefin and (2) a mercaptan, the --SH group of said mercaptan joining to a carbon-carbon double bond of said olefin, attaching the H of said --SH group to one of the double-bonded carbons and attaching the S of said --SH group to the other of the double-bonded carbons, the carbons to which said S is attached in said lubricant compound being saturated, said lubricant compound having at least one free carboxyl group or salt of a free carboxyl group, said lubricant compound being present at between about 0.05 and about 5 parts by weight per 100 parts of said resin.
A thermoplastic resin composition comprising a halogen-containing thermoplastic resin and a lubricant compound having the formula:
- ##STR24## wherein C.sub.m, C.sub.n, C.sub.o, C.sub.p, and C.sub.q are straight or branched, saturated or unsaturated carbon chains with the number of carbons designated by the subscripted letter or hydrogen wherein the subscripted letter equals 0, and m+n+o+p+q are greater than or equal to 29, said S being attached to saturated carbons, said lubricant compound being present at between about 0.05 and about 5 parts by weight per 100 parts of said resin.
A method of preparing a resin composition comprising blending particulates of a halogen-containing thermoplastic resin with a lubricant compound which is an addition product of (1) an olefin and (2) a mercaptan, and which contains at least one free carboxyl group or a salt of a free carboxyl group, the --SH group of said mercaptan joining to a carbon-carbon double bond of said olefin, attaching the H of said --SH group to one of the double-bonded carbons and attaching the S of said --SH group to the other of the double-bonded carbons, the carbons to which said S is attached in said lubricant compound being saturated, said lubricant compound being provided at about 0.05 to about 5 parts per 100 parts by weight of said resin, heating said blend to fuse the same and forming said fused composition.
A method of preparing a resin composition comprising blending particulates of a halogen-containing thermoplastic resin with a lubricant compound having the formula:
- ##STR30## wherein C.sub.m, C.sub.n, C.sub.o, C.sub.p, and C.sub.q are straight or branched, saturated or unsaturated carbon chains with the number of carbons designated by the subscripted letter or hydrogen wherein the subscripted letter equals 0, and m+n+o+p are greater than or equal to 29, said S being attached to saturated carbons, said lubricant compound being provided at about 0.05 to about 5 parts per 100 parts by weight of said resin, heating said blend to fuse the same and forming said fused composition.
Dependencies are inferred from the claim text.