A printing member for electrostatic photocopying, comprising:
- a substrate having a conductive surface;
- and
- a photo-electrically-sensitive, electrically chargeable layer on the conductive surface of the substrate;
- wherein the photo-electrically-sensitive, electrically chargeable layer has (a) a first layer member formed on the conductive surface of the substrate, the first layer member having a P or N or I type first non-single-crystal semiconductor layer or a first semi-insulating or insulating layer, (b) a second layer member formed on the first layer member, the second layer member being a first laminate member having an I type second non-single-crystal semiconductor layer and an I type third non-single-crystal semiconductor layer having smaller energy band gap than that of the second non-single-crystal semiconductor layer, and (c) a third layer member formed on the second non-single-crystal semiconductor layer, the third layer member having an I type fourth non-single-crystal semiconductor layer having equal to or larger energy band gap than that of the second non-single-crystal semiconductor layer, or a second semi-insulating or insulating layer, or a second laminate member having the fourth non-single-crystal semiconductor layer or second semi-insulating layer and the insulating layer;
- and
- wherein the third non-single-crystal semiconductor layer has a higher degree of crystallization than does the second non-single-crystal semiconductor layer.