Process for the preparation of dodecamethylenebismelamine and the use thereof
AssigneeDegussa AG
InventorsPeter Werle, Holger Focke, Alwin Boes
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Abstract
The invention relates to a process for preparing dodecamethylenebismelamine (DMB) by reacting 2,4-diamino-6-chloro-1,3,5-triazine with 1,12-diaminododecane in an alkaline aqueous suspension, to which the diamine has been added in a water-miscible solvent. The product is used to stabilize aqueous formaldehye solutions.
Claims2
A process for the stabilization of aqueous formaldehyde solutions comprising introducing into said formaldehyde solutions a sufficient amount of dodecamethylenebismelamine in the form of a 15 to 25 weight percent solution, based on the total amount, wherein methoxymethanol (methyl hemiformal) is used as a solvent in form of a methanolic solution with a methoxymethanol content of 70-85%.
A process for the stabilization of aqueous formaldehyde solutions, comprising introducing a sufficient amount of dodecamethylenebismelamine into an aqueous formaldehyde solution wherein the bismelamine is a 15 to 25 weight percent solution, based on the total amount, and methoxymethanol (methyl hemiformal) is used as solvent in form of a methanolic solution with a methoxymethanol content of 70-85%, said dodecamethylenebismelamine having been prepared by a process comprising reacting 2,4-diamino-6-chloro-1,3,5-triazine with 1,12-diaminododecane as reactants in an alkaline, aqueous suspension, said 1,12-diaminododecane having been dissolved in a water-miscible, organic solvent and then added to said suspension, carrying out the reaction at reflux temperature, cooling the formed reaction mixture to room temperature and separating the resulting crystallized dodecamethylenebismelamine product.
Dependencies are inferred from the claim text.