Oxidation resistant ferrous base foil and method therefor
AssigneeArmco Inc.
InventorsFarrell M. Kilbane, F. Curtiss Dunbar
Life of this patent
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Abstract
Aluminum coated ferritic base metal foil formed by cold reduction of hot dip aluminum coated ferritic steel strip containing from 10% to about 35% chromium, up to 3% aluminum, and up to 1% silicon, the foil having a ratio of aluminum coating thickness on both sides to base metal foil thickness of at least 1:10, with at least 4% by weight total aluminum. The method of production includes heating the foil in an oxidizing atmosphere within specified temperature and time limitations to provide a porous surface having a thin layer of aluminum oxide. The foil is adapted for fabrication into monolithic support structures for catalytic converters for internal combustion engine exhaust systems.
Claims6
A method of making an aluminum coated ferrous base metal foil having improved oxidation resistance at elevated temperatures, improved wet corrosion resistance, and surfaces adapted to bond securely to a ceramic, heat resistant catalyst support material, comprising the steps of:
- hot dip coating a ferritic base metal strip in a bath of molten aluminum, said strip having a thickness of at least 0.25 mm and containing from 10% to about 35% chromium, up to 3% aluminum, up to 1% silicon, and balance essentially iron;
- finishing the molten aluminum coating to provide a coating thickness ranging from 0.013 to 0.13 mm on each side and a total aluminum content of at least 4% by weight;
- cold reducing the aluminum coated strip to a foil having a thickness not greater than 0.13 mm without intermediate annealing wherein the ratio of total aluminum coating thickness to base metal thickness is at least 1:10;
- and
- heating said foil in an oxidizing atmosphere within the range of about 600.degree. to about 1200.degree. C. with a time at temperature ranging from about 1 second to about 1 hour in accordance with the relationship:
- 1210>temperature (.degree.C.)+1/6.times.time (seconds)>600,
- whereby to produce a porous surface having a matte gray appearance.
Dependencies are inferred from the claim text.