Ethylene oxide catalyst
AssigneeShell Oil Company
InventorsGosse Boxhoorn, Aan H. Klazinga, Otto M. Velthuis
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Abstract
This invention relates to ethylene oxide catalysts comprising silver, alkali metal promoters supported on a carrier, which carrier is prepared by a process which comprises mixing an aluminum compound with an alkali metal salt and with a silicon compound and calcining resultant mixture at a temperature greater than about 1100.degree. C.
Claims13
A catalyst for the production of ethylene oxide from ethylene and molecular oxygen which comprises silver and an alkali metal promoter supported on a carrier, which carrier is prepared by a process which comprises mixing an aluminum compound with water and an alkali metal salt and with silicon dioxide and calcining the resultant mixture at a temperature between 1200.degree. C. and 1700.degree. C.
A catalyst for the production of ethylene oxide from ethylene and molecular oxygen which comprises about 1-25 wt % silver (basis total catalyst) and about 20-1000 ppm (measured as the metal, basis total catalyst) of an alkali metal promoter supported on a carrier, which carrier is prepared by process which comprises mixing an aluminum compound with water and an alkali metal salt and with silicon dioxide wherein the atom ratio of the alkali metal in the alkali metal salt/aluminum is between about 0.001 and about 0.1 and the silicon/aluminum atom ratio is between about 0.1 and about 0.5, and calcining the resultant mixture at a temperature between about 1200.degree. C. and about 1700.degree. C.
A catalyst for the production of ethylene oxide from ethylene and molecular oxygen which comprises about 1-25 w % silver (basis total catalyst) and about 20-1000 ppm (measured as the metal, basis total catalyst) of an alkali metal promoter supported on a carrier, which carrier is prepared by a process which comprises mixing boehmite and/or gamma-alumina, water, an alkali metal salt, silicon dioxide wherein the atom ratio of the alkali metal of the alkali metal salt/aluminum is between about 0.001 and about 0.1 and the silicon/aluminum ratio is between about 0.1 and about 0.5, the resulting mixture being extruded to shaped carrier particles which are then calcined at a temperature about 1200.degree. C. and about 1700.degree. C.
Dependencies are inferred from the claim text.