Trona-enhanced steam foam oil recovery process
AssigneeShell Oil Company
InventorHon C. Lau
Life of this patent
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Abstract
In a continuous or cyclic steam foam drive, recovery of an acidic reservoir oil (1) is improved by injecting steam accompanied by (a) enough dissolved alkaline monovalent salt to ion-exchange multivalent cations from the reservoir rocks and precipitate those ions in compounds which are insoluble in an alkaline aqueous liquid as well as forming soaps of the reservoir oil acids and (b) surfactants for foaming the steam and increasing the salt tolerance of an aqueous surfactant system containing the soaps of the reservoir oil acids, and (2) is further improved by using trona or an equivalent mixture of alkali metal carbonates and bicarbonates as the alkaline monovalent salt.
Claims9
In a process in which steam and steam-foaming surfactant are injected into a subterranean reservoir for displacing a relatively acidic oil toward a production location, which process includes injecting into the reservoir, at least as soon as at least some portion of the steam is injected, (a) a kind and amount of water soluble, alkaline material effective for ion-exchanging multivalent ions from the reservoir rocks and precipitating compounds containing those ions and for causing the aqueous liquid phase of the injected fluid to form soaps of substantially all of the petroleum acids in the reservoir oil, and (b) at least one surfactant arranged for foaming the steam and providing a preformed cosurfactant material capable of increasing the salinity requirement of an aqueous surfactant system in which soaps derived from the reservoir oil comprise a primary surfactant, an improvement comprising:
- using as said water soluble alkaline material, a material consisting essentially of a substantially equal molar mixture of alkali metal carbonates and bicarbonates which is, or is substantially equivalent to, trona.
Dependencies are inferred from the claim text.