Process for preparing benzophenone-azines
AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsTakanari Nawata, Shuzabu Sakaguchi, Toshiaki Kohzaki, Osamu Aoki, Norio Takeda, Yoshiyuki Aoki, Masafumi Shimpo
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AssigneeMitsubishi Gas Chemical Company, Inc.
InventorsTakanari Nawata, Shuzabu Sakaguchi, Toshiaki Kohzaki, Osamu Aoki, Norio Takeda, Yoshiyuki Aoki, Masafumi Shimpo
Estimating the term…
A process for continuously preparing benzophenone-azines comprising oxidizing benzophenone-imines with molecular oxygen or a molecular oxygen-containing gas in the presence of a copper halide catalyst is disclosed. The oxidation reaction is carried out in a multistage system under an oxygen partial pressure gradually decreasing from the former stage to the latter stage and at a conversion gradually decreasing from the former stage to the latter stage, while controlling the conversion so that the molar ratio of the benzophenone-imines to the copper halide in the final stage be maintained at 1 or more. By the process, the continuous reaction can stably be performed at a high conversion of the benzophenone-imines without involving insolubilization and sedimentation of the catalyst.
A process for continuously preparing benzophenone-azines comprising oxidizing benzophenone-imines with molecular oxygen or a molecular oxygen-containing gas in the presence of a copper halide catalyst, wherein the oxidation reaction is carried out in a multistage system under an oxygen partial pressure decreasing from the former stage to the latter stage and at a conversion gradually decreasing from the former stage to the latter stage, while controlling the conversion so that the molar ratio of the benzophenone-imines to the copper halide in the final stage be maintained at from 1 to 3, wherein the partial pressure of oxygen is lower in the latter stage than in the former stage within such a range that the partial pressure of oxygen in the final stage is from 0.1 to 1 atm and that in the former stage or stages is from 0.3 to 10 atm, and wherein the conversion in the final stage is from 5 to 30% and wherein the molar ratio of the benzophenone-imines to the copper halide in the former stage or stages is from 2 to 20.
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