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US 4,727,175 AGranted
Hydroxyphenoxyphosphazenes and a process for producing same
AssigneeThe Dow Chemical Company
InventorMassimo D. Bezoari
Life of this patent
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Abstract
This invention relates to R.sub.1, R.sub.2 -hydroxyphenoxycyclotriphosphazenes and to a process for their preparation. R.sub.1 is a phenoxy-, halophenoxy- or an isopropoxy- group while R.sub.2 is a hydroxyphenoxy- or a bis-phenoxy A group. The process comprises reacting R.sub.1 -chlorocyclotriphosphazene with an R.sub.2 salt. The reaction takes place in the presence of an inert organic solvent and at a temperature within the range of from about 20.degree. C. to about 150.degree. C.
Claims22
A process for the production of a compound of the formula,
- N.sub.3 P.sub.3 (R.sub.1).sub.n (R.sub.2).sub.6-n
- wherein R.sub.1 is an isopropoxy radical having the formula ##STR7## or an aryloxy radical having the formula ##STR8## wherein each Z is independently selected for each isopropoxy radical from F and H, each X is independently selected for each aryloxy radical from Cl, Br, F and H, wherein n is a whole integer which is .gtoreq.1 and .ltoreq.5, and wherein R.sub.2 is ##STR9## or is a hydroxyphenoxy radical having the formula:
- ##STR10## in which Y is selected from Cl, Br, F and H, said process comprising, reacting an R.sub.1 -chlorocyclotriphosphazene having n R.sub.1 substituents and 6-n chloride constituents and an R.sub.2 salt for a time period sufficient to yield said compound, said reaction occurring in an inert organic solvent medium, at a temperature within the range of from about 20.degree. C. to about 150.degree. C., and with a molar ratio of said R.sub.1 -chlorocyclotriphosphazene to the R.sub.2 anion component of said R.sub.2 salt of 1:b, wherein b>5-n.
Compounds of the formula,
- N.sub.3 P.sub.3 (R.sub.1).sub.n (R.sub.2).sub.6-n
- wherein R.sub.1 is an isopropoxy radical having the formula ##STR11## or an aryloxy radical having the formula ##STR12## wherein n is a whole integer which is .gtoreq.1 and .ltoreq.5, each Z is independently selected for each isopropoxy radical from F and H, each X is independently selected for each aryloxy radical from Cl, Br, F and H, and wherein R.sub.2 is ##STR13## or is a hydroxyphenoxy radical having the formula:
- ##STR14## in which each Y is independently selected for each hydroxyphenoxy radical from Cl, Br, F and H.
Dependencies are inferred from the claim text.