Polyimide gas separation membranes
AssigneeE. I. Du Pont de Nemours and Company
InventorRichard A. Hayes
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Abstract
Semi-flexible aromatic polyimides, prepared by polycondensation of dianhydrides with diamines having alkyl substituents on all ortho positions to the amine functions, or with mixtures of diamines, some components having substituents on all positions ortho to the amine functions, are disclosed. Membranes formed from this class of polyimides have improved environmental stability and superior gas permeability. The range of gas permeation properties observed allows for the tailoring of membrane material for widely diverse gas separations. The high permeabilities of some gases from multicomponent mixtures is due to the optimization of the molecular free volume in the polymer.
Claims7
A process for separating gases comprising bringing two or more gases under pressuer into contact with a membrane formed of an aromatic polyimide comprising units of the formula ##STR11## where --Ar-- is ##STR12## or mixtures thereof, R is ##STR13## or mixtures thereof, --Ar'-- is ##STR14## or mixtures thereof, ##STR15## is ##STR16## or mixtures thereof, and --R"-- is ##STR17## where n=0 to 4, alkylene radicals of 1 to 3 carbon atoms or mixtures thereof,
- --X, --X.sub.1, --X.sub.2, and --X.sub.3 are independently alkyl groups having 1 to 6 carbon atoms preferably methyl or ethyl, or aromatic groups of 6 to 13 carbon atoms,
- Z is --H, --X, --X.sub.1, --X.sub.2, or --X.sub.3
- W is 5% to 100%
- Q is 5% to 100%
- Y is 100% minus W
- V is 100% minus V
- Y plus V is at least 5%, whereby at least one of said gases is enriched upon permeating the membrane.
A gas separation membrane formed of an aromatic polyimide comprising units of the formula ##STR19## where --Ar-- is ##STR20## or mixtures thereof, --R-- is ##STR21## or mixtures thereof, --Ar'-- is ##STR22## or mixtures thereof, ##STR23## is ##STR24## or mixtures thereof, and --R"-- is ##STR25## where n=0 to 4, alkylene radicals of 1 to 3 carbon atoms or mixtures thereof,
- --X, --X.sub.1, --X.sub.2, and --X.sub.3 are independently alkyl groups having 1 to 6 carbon atoms preferably methyl or ethyl, or aromatic groups of 6 to 13 carbon atoms,
- Z is --H, --X, --X.sub.1, --X.sub.2, or X.sub.3
- W is 5% to 100%
- Q is 5% to 100%
- Y is 100% minus W
- V is 100% minus V
- Y plus V is at least 5%.
Dependencies are inferred from the claim text.