US 4,708,854 AGranted

Process for the removal of NO from fluid streams using a water-soluble polymeric chelate of a polyvalent metal

AssigneeThe Dow Chemical Company

InventorRobert R. Grinstead

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Abstract

The present invention relates to a cyclic continuous process and compositon for the removal of NO and SO.sub.2 from a variety of fluid streams. A fluid stream containing NO and SO.sub.2 is contacted with an aqueous solutin of water-soluble organic polymeric chelate containing a polyvalent metal, e.g., Fe (II). The NO is catalytically absorbed and in the presence of SO.sub.2, the imidodisulfonate is formed. Optionally, a reducing agent, such as sodium hydrogen sulfide, is added to maintain the polyvalent metal in the reduced state. The process next includes removal of the imidodisulfonate formed. The separation of water and low molecular weight materials and products, e.g. molecular weight below 500, usually occurs by ultrafiltration or dialysis, with recycle and re-use of the polyvalent metal chelate.

Claims17

Dependent claims

A cyclic process for the removal of NO from a fluid stream comprising mixtures of NO and SO.sub.2, which process comprises:

(A) contating the fluid stream in a contacting zone with an aqueous reaction solution at a temperature between about 10.degree. and 90.degree. C., the reaction solution itself comprising an effective amount of an organic water-soluble polymeric chelate wherein the chelate contains a polyvalent metal to absorb the NO present, wherein the polymeric chelate has a molecular weight of between about 500 and 1,000,000, and a backbone repeating unit polymer chain having pendant organic chemical groups able to chelate the metal ion present;
and
(B) separating the gas stream and the resulting aqueous phase produced in step (A) containing the polymeric chelate and imidodisulfonate;
(C) separating and purifying the aqueous solution produced in step (B) by membrane separation means effective to remove a portion of the water and other monomeric reaction products having a molecular weight of less than 500;
and
(D) recycling the concentrated aqueous solution containing the water-soluble polymeric chelate of step (C) to the contacting zone of step (A).

3 more elements

A process for the removal of NO from a fluid stream comprising mixtures of NO and SO.sub.2, which process comprises:

(A) contacting the fluid stream in a contacting zone with an aqueous reaction solution at a temperature of between about 10.degree. and 90.degree. C., the reaction itself comprising an effective amount of a water-soluble organic polymeric chelate, containing a polyvalent metal to absorb the NO present, wherein the polymeric chelate has a molecular weight of between about 500 and 1,000,000 and pendant chelating groups is selected from chelates of the formula:
##STR15## wherein R is --CH.sub.2 COOH, --CH.sub.2 CH.sub.2 COOH, --CH.sub.2 --P(=O)(0H).sub.2, ##STR16## wherein R.sub.1 and R.sub.2 are independently --CH.sub.3, --SO.sub.3 H, --Cl, --H, --COOH, and m is an integer between about 5 and 20,000;
##STR17## wherein R.sub.3, R.sub.4 and R.sub.5 are each independently selected from R wherein R is as defined hereinabove, m is an integer between about 5 and 20,000;
and n is 0, 1, 2, 3 or 4;
##STR18## wherein R.sub.3, R.sub.4 and R.sub.5 are as defined hereinabove;
r is an integer between about 10 and 20,000, s is an integer between about 1 and 4;
##STR19## wherein R.sub.3, R.sub.4 and R.sub.5 are as defined hereinbove;
t is an integer between about 10 and 20,000 and x is an integer between about 1 and 4;
##STR20## wherein R.sub.3, R.sub.4 and R.sub.5 are as defined hereinabove, y is an integer between about 10 and 20,000;
z is an integer between about 1 and 4;
##STR21## where R.sub.3, R.sub.4 and R.sub.5 are as defined hereinabove, where x is between about 10 to 10,000, a is about 6, b is between about 1 and 4, and c is between about 1 and 4;
##STR22## where m, x, n and R.sub.3, R.sub.4 and R.sub.5 are as defined hereinabove;
or ##STR23## wherein R.sub.3, R.sub.4 and R.sub.5 are as defined hereinabove;
and w is between about 2000 and 4000;
(B) separating the fluid stream and the resulting aqueous phase containing the polymeric chelate . iron (II) and imidodisulfonate of step (A);
(C) concentrating the aqueous phase repeated in step (B) by membrane separation means effective to remove a portion of the water and other monomeric reaction products having a molecular weight below 500 and;
(D) recycling the concentrated aqueous solution containing the water soluble polymeric chelate produced in step (C) to the contacting zone of step (A).

14 more elements

Dependencies are inferred from the claim text.