A chemical vapour deposition (CVD) method for manufacturing a diamond clad composite body by depositing one or, successively, further adherent polycrystalline diamond layers substantially free from intercrystalline binder on (I) a core substrate selected from (a) metal bonded hard metallic compounds, (b) ceramic materials and (c) metals or alloys, said method involving contacting the heated core with an activated gaseous mixture of hydrocarbon and hydrogen, characterized in that said mixture is activated by passing over a tantalum heater to a temperature of 1500.degree. to 2500.degree. C.