US 4,701,429 AGranted

Catalyst regeneration with varying air flow to burn-off zone from drying zone through halogenation zone

AssigneeUop LLC

InventorArthur R. Greenwood

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Abstract

Method for effecting multiple treatment steps needed to regenerate spent hydrocarbon conversion catalyst. Catalyst is contacted with a hot oxygen-containing gas stream in order to remove coke which accumulates on the catalyst while it is in a hydrocarbon conversion zone. After the coke is burned off in a combustion zone, catalyst is passed into a halogenation zone wherein a halogen is deposited on the catalyst. Catalyst leaving the halogenation zone is passed into a drying zone for removal of water formed in the combustion zone which has remained on the catalyst instead of being carried off with combustion gases. Water removal is accomplished by passing a hot dry air stream through the catalyst in the drying zone. A portion of the air stream which has passed through the drying zone is passed through the halogenation zone in admixture with a halogen, while the balance of the air stream leaving the drying zone is removed from the regeneration apparatus by venting it to the atmosphere or another disposal location. That portion of the air stream which is utilized in the halogenation zone is then passed into the combustion zone where it provides the oxygen required to accomplish burning of the carbon. The flow of air into the drying zone is controlled at a rate established to accomplish the degree of desired drying. The oxygen content of the gas flowing to the burn-off zone is monitored and the amount of gas vented from the drying zone is adjusted in order to maintain the desired concentration of oxygen. In this manner, the amount of air supplied to the burn-off zone is adjusted independently of the air supplied to the drying zone.

A method for effecting regeneration of spent catalyst particles used in hydrocarbon conversion reactions comprising:

(a) passing spent catalyst particles through a burn-off zone, by means of gravity, which is maintained at a coke-oxidizing temperature, wherein said catalyst is contacted with a recycle gas comprising oxygen;
(b) passing catalyst leaving said burn-off zone through a halogenation zone, by means of gravity, wherein said catalyst is contacted with a halogenation gas comprising a halogen compound;
(c) passing catalyst leaving said halogenation zone through a catalyst drying zone, by means of gravity, wherein water is removed from said catalyst;
(d) compressing an air stream drawn from the atmosphere to an elevated pressure;
(e) passing said compressed air stream, at a previously determined flow rate, through an air drying zone wherein water is removed from said air stream and heating said air stream;
(f) passing said heated and dried air stream upward through said catalyst drying zone in countercurrent contact with catalyst, thereby removing the water from the catalyst;
(g) withdrawing a first portion of the air stream emanating from said drying zone catalyst and mixing a halogen compound with it to form said halogenation gas;
(h) passing said halogenation gas into contact with catalyst in said halogenation zone;
(i) withdrawing halogenation gas from contact with said halogenation zone catalyst and mixing it with gas emanating from said burn-off zone catalyst to form said recycle gas;
(j) passing said recycle gas through the catalyst in said burn-off zone to effect combustion of coke deposits on the catalyst;
(k) withdrawing a second portion of the air stream emanating from the drying zone catalyst, where said first and second portions constitute the whole of the air stream emanating from the drying zone catalyst;
and,
(l) measuring the oxygen content of said recycle gas and varying the flow rate of said second portion of the air stream emanating from the drying zone, thereby varying the amount of air supplied to the burn-off zone from the drying zone by means of the halogenation zone.

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Facts

Application

06/920,556Filed 20 Oct 1986 · division

Priority

3 Feb 1986

Granted

20 Oct 1987

Term ends

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Classification5 codes

C10G 35/12
With moving catalysts: according to the "moving-bed" method
B01J 8/08
Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes: with moving…
B01J 38/26
Moving bed, e.g. vertically or horizontally moving bulk: having mainly counter-current flow of oxygen-containing gas and material
C10G
Cracking hydrocarbon oils

Abstract

Claims5