Highly active and highly selective aromatization catalyst
AssigneeChevron Research Company
InventorsDonald S. Santilli, John J. Long, Robert T. Lewis
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AssigneeChevron Research Company
InventorsDonald S. Santilli, John J. Long, Robert T. Lewis
Estimating the term…
A highly selective zeolitic reforming catalyst is disclosed that contains a promoter selected from the group consisting of iron, cobalt, and titanium; and that has a platinum to promoter weight ratio of less than 10:1. In one embodiment a type L zeolite is formed by combining an aqueous solution of potassium hydroxide, aluminum hydroxide, and ferric nitrate with an aqueous solution of silica to form a thickening gel in a mother liquor; heating the thickening gel to form a type L zeolite; cooling the solution containing the type L zeolite; decanting the mother liquor from the solution; filtering the type L zeolite from the solution; washing the filtered type L zeolite so that the pH of the wash is about 101/2; and drying the washed type L zeolite. The catalyst is formed by adding platinum to the dried type L zeolite by pore fill impregnation with an aqueous solution of Pt(NH.sub.3).sub.4 (NO.sub.3).sub.2 to form a catalyst; drying the catalyst and calcining the catalyst.
A reforming catalyst comprising an L zeolite containing platinum metal and at least one promoter metal selected from the group consisting of iron, cobalt, titanium, and rare earth metal wherein said catalyst has a platinum to promoter metal mole ratio of less than 10:1.
A reforming catalyst comprising an L zeolite containing platinum metal and at least one promoter metal selected from the group consisting of iron, cobalt, titanium, and rare earth metal wherein said catalyst has as platinum to promoter metal mole ratio of less than 10:1 and the promoter cation is present on the L zeolite prior to the reduction of platinum to a zero valence state.
Dependencies are inferred from the claim text.