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US 4,681,592 AGranted
Peracid and bleach activator compounds and use thereof in cleaning compositions
AssigneeThe Procter & Gamble Company
InventorsFrederick E. Hardy, Barry T. Ingram
Life of this patent
Estimating the term…
Abstract
Per-acids and per-acid precursor compounds of the general type RXAOOH and RXAL, wherein R is a hydrocarbyl group, X is a hetero-atom. A is a carbonyl bridging group and L is a leaving group, especially oxybenzenesulfonate, are useful bleaching compounds for fabrics. Laundry products containing same are disclosed.
Claims22
Peracids of the formula:
- [RX].sub.m AOOH
- wherein
- R is hydrocarbyl, selected from the group consisting of optionally substituted, linear and branched C.sub.6 -C.sub.20 alkyl and alkenyl and C.sub.6 -C.sub.20 alkyl-substituted aryl;
- or alkoxylated hydrocarbyl;
- X is selected from the group consisting of O, SO.sub.2, N(R').sub.2, P(R').sub.2, (R')P.fwdarw.O and (R')N.fwdarw.O;
- m is either 1 or 2;
- and wherein for m=1, A is selected from the group consisting of ##STR6## where x is an integer from 0 to 4;
- z is an integer from 0 to 2;
- (R') is alkyl and R" is branched-chained alkylene and wherein for m=2, A is ##STR7##
6 more elements
A bleach activator compound of the formula
- [RX].sub.m AL
- wherein R is hydrocarbyl, selected from the group consisting of optionally substituted, linear and branched C.sub.6 -C.sub.20 alkyl and alkenyl and C.sub.6 -C.sub.20 alkyl-substituted aryl;
- or alkoxylated hydrocarbyl;
- X is selected from the group consisting of O, SO.sub.2, N(R').sub.2, P(R').sub.2, (R')P.fwdarw.O and (R')N.fwdarw.O;
- m is either 1 or 2;
- and wherein for m=1, A is selected from the group consisting of ##STR8## where x is an integer from 0 to 4;
- z is an integer from 0 to 2;
- (R') is alkyl and R" is branched-chain alkylene and wherein for m=2, A is ##STR9## and wherein L is a leaving group selected from the group consisting of:
- ##STR10## wherein x is an integer from 0 to 8,
- Z is H, R.sub.2 or halide,
- R.sub.2 is C.sub.1 -C.sub.4 alkyl, and
- Y is selected from
- --SO.sub.3 M
- --OSO.sub.3 M
- 13 CO.sub.2 M
- --N.sup.+ (R.sub.2).sub.3 Q.sup.-
- --N(R.sub.2).sub.2 .fwdarw.O
- wherein M is H, alkali metal, alkaline earth metal, ammonium or substituted ammonium and Q is halide or methosulphate.
15 more elements
Dependencies are inferred from the claim text.