Production of light olefins
AssigneeUnion Carbide Corporation
InventorSteven W. Kaiser
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Abstract
The process for the production of light olefins from a feedstock comprising at least an aliphatic hetero compound comprising contacting said feedstock in the presence of an aromatic diluent with a silicoaluminophosphate molecular sieve at effective process conditions to produce light olefins.
Claims38
The process for making light olefins containing 2 to 4 carbon atoms which comprise contacting a feedstock comprising one or more aliphatic hetero compounds with a silicoaluminophosphate molecular sieve in the presence of a diluent wherein the silicoaluminophosphate molecular sieve comprises a microporous crystalline silicoaluminophosphate whose unit empirical formula in the as-synthesized and anhydrous form is
- mR:(Si.sub.x Al.sub.y P.sub.z)O.sub.2
- wherein "R" represents at least one organic templating agent present in the intracrystalline pore system;
- "m" has a value of from 0.02 to 0.3;
- "m" represents the moles of "R" present per mole of (Si.sub.x Al.sub.y P.sub.z)O.sub.2 ;
- "x", "y" and "z" represent the mole fractions of silicon, aluminum and phosphorus respectively, present as tetrahedral units, said mole fractions being such that they are within the pentagonal compositional area defined by points A, B, C, D and E of the ternary diagram which is FIG. 1, at effective process conditions to produce said light olefins, comprising the improvement of correlating the diluent to the silicoaluminophosphate whereby the average kinetic diameter of the diluent molecules is greater than the average pore size of the silicoaluminophosphate molecular sieve.
Dependencies are inferred from the claim text.