Lamellar iron oxide pigments, a process for the production thereof and the use thereof
AssigneeBayer Aktiengesellschaft
InventorsGerhard Franz, Lothar Schonfelder, Heinrich Heine
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AssigneeBayer Aktiengesellschaft
InventorsGerhard Franz, Lothar Schonfelder, Heinrich Heine
Estimating the term…
In the production of an .alpha.-iron oxide pigment by the hydrothermal treatment of a trivalent iron-containing solution or suspension, the improvement which comprises adding to the solution or suspension prior to the hydrothermal treatment active .alpha.-iron oxide seeds with lamellar or disc-like crystal form and a specific surface of at least 10 m.sup.2 /g, whereby the resulting pigment is lamellar with an Fe.sub.2 O.sub.3 content of at least 88%, an average particle diameter of from 0.5 to 20 .mu.m, an average ratio of diameter to thickness of from 20 to 100, and an almost normally distributed particle size distribution, the relative standard deviation of which, based on the average value of the normal distribution, is less than 0.3. The product has superior coloring properties and is used as a precursor compound for the production of lamellar magnetic pigments with superior magnetic properties.
Lamellar pigments consisting of .alpha.-iron oxide with an Fe.sub.2 O.sub.3 content of at least 88%, an average particle diameter of from 0.5 to 20 .mu.m, an average ratio of diameter to thickness of from 20 to 100, and an almost normally distributed particle size distribution, the relative standard deviation of which, based on the average value of the normal distribution, is less than 0.3.
In the production of an .alpha.-iron oxide pigment by the hydrothermal treatment of a trivalent iron-containing solution or suspension, the improvement which comprises adding to the solution or suspension prior to the hydrothermal treatment active .alpha.-iron oxide seeds with lamellar or disc-like crystal form and a specific surface of at least 10 m.sup.2 /g, whereby the resulting pigment is lamellar with an Fe.sub.2 O.sub.3 content of at least 88%, an average particle diameter of from 0.5 to 20 .mu.m, an average ratio of diameter to thickness of from 20 to 100, and an almost normally distributed particle size distribution, the relative standard deviation of which, based on the average value of the normal distribution, is less than 0.3.
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