Melt-processible tetrafluoroethylene/perfluoroolefin copolymer granules and processes for preparing them

A process for treating a melt-processible, substantially nonelastomeric tetrafluoroethylene copolymer, which treatment comprises in sequence

• A. coagulating from its aqueous polymerization medium a melt-processible tetrafluoroethylene copolymer comprising recurring units of 80 to 98 mole % tetrafluoroethylene and complementally 2 to 20 mole % of at least one perfluoroolefin of 3-8 carbon atoms, wherein coagulation is carried out by causing the copolymer and medium to form a viscous gel by mechanical agitation or alternatively by addition of a chemical gelation agent, after which the resulting gel is broken into granules by addition of an essentially water-immiscible liquid accompanied by mechanical agitation,
• B. separating the coagulated copolymer from the aqueous medium,
• C. removing liquid from the separated copolymer by drying, and
• D. hardening by heating the dried copolymer at a temperature between 25.degree. C. below its differential scanning calorimeter unit onset temperature and its initial melt endotherm peak temperature until the attrition factor of the particles is less than 60, but before the D.sub.50 of the particles increases by more than 20%.