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AssigneeMetallgesellschaft Aktiengesellschaft
InventorsGerfried Unger, Helmut Untucht, Wolfgang Winterstein
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A solvent-containing composition for the cleaning of equipment used to mix and handle reactive multicomponent mixtures of high viscosity, which react to form polymers. In order to improve the capacity of the solvent to dissolve the more or less polymerized mixtures, the solvent contains a chain-terminating agent. For binary systems containing liquid polysulfide polymers, the solvent contains a chain-terminating agent or chain-degrading agent containing mercapto group-containing compounds of the general formula R--SH or disulfide or polysulfide group-containing compounds of the general formula R--S.sub.n --R, in which formulas n.gtoreq.2 and R represents equal or difficult alkyl residues, aryl residues or substituted alkyl or aryl residues. For binary polyurethane systems, the solvent contains chain-terminating compounds which in their molecule contain a Zerewitinoff-active hydrogen atom and have the general formula HY--R.sup.1, wherein ##STR1## where R.sup.2 =H or alkyl and R.sup.1 is an organic radical which will not enter into polyaddition or polycondensation reactions with itself or with isocyanate groups.
A method of removing a polymeric residue from process equipment used in the handling and mixing of reactive multicomponent mixtures of liquid polysulfide polymers which react to form rubberlike high-polymeric polysulfide polymers, said method comprising the step of reacting residues of said high-polymeric polysulfide polymers with a solution of:
A method of removing from process equipment used in the manufacture of liquid polysulfide polymers, a polymeric residue, which comprises the step of contacting said polymeric residue, with a 0.5 to 30 weight % solution of a polymerization inhibiting compound selected from the group consisting of 2-mercapto-ethanol, and mercaptoacetic acid-2-ethoxyethyl ester in a solvent selected from the group consisting of methylene dichloride, ethyl acetate, toluene, methylethyl ketone, dioxane, and dimethyl sulfoxide, in the presence of a catalytically effective amount of a promoter selected from the group consisting of triethylamine, dibutylamine and hexamethylene diamine.
A method of removing from process equipment used in the manufacture of polyurethanes, a polymeric residue, which comprises the step of contacting said polymeric residue, which comprises the step of contating said polymeric residue with a 0.5 to 30 weight % solution of a polymerization inhibiting compound selected from the group consisting of diethylamine, dibutylamine, methyl-stearyl-amine, and toluene-4-sulfonyl-isocyanate, in methylene dichloride.
Dependencies are inferred from the claim text.