US 4,668,752 AGranted

Linear ethylene copolymer

AssigneeMitsui Petrochemical Industries, Ltd.

InventorsKenichi Tominari, Hiroshi Inoue, Masayuki Sakai

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Abstract

Ethylene/C.sub.4 -C.sub.20 alpha-olefin copolymers are disclosed which have new characteristics in regard to composition distribution, degree of branching, randomness and crystallinity by DSC melting points. These copolymers have excellent transparency, impact strength, tear strength, blocking resistance, environmental stress cracking resistance, heat resistance and low-temperature heat sealability in a well-balanced combination when they have a density of at least 0.90. When their density is less than 0.90, these copolymers have particularly excellent transparency, impact strength and low-temperature heat sealability, and by incorporating them in various thermoplastic resins, they serve as an excellent modifier for improved impact strength and low-temperature heat sealability.

A copolymer of ethylene with at least one C.sub.4 -C.sub.20 .alpha.-olefin having the following characteristics (A) to (J)

(A) it has a melt flow rate, determined by ASTM D 1238E, of from 0.01 to 200 g/10 min.,
(B) it has a density of from 0.880 to less than 0.900 g/cm.sup.3
(C) it has a composition distribution parameter (U), defined by the following equation (1)
U-100.times.(Cw/Cn-1) (1)
wherein Cw is the weight average degree of branching, and Cn is the number average degree of branching,
of not more than 50,
(D) the amount of components having a degree of branching of not more than 2/1000 carbons is not more than 10% by weight based on the ethylene copolymer,
(E) the amount of components having a degree of branching of at least 30/1000 carbons is not more than 70% by weight based on the ethylene copolymer,
(F) the ratio of the average block methylene chain length to the average methylene chain length is not more than 2.0,
(G) it has n melting points measured by a differential scanning calorimeter (DSC) (wherein n=1 or n.ltoreq.3), in which the highest melting point (T.sub.1) among these DSC melting points is given by the following expression (i)
(175.times.d-46).degree.C..ltoreq.T.sub.1 .ltoreq.125.degree. C. (i)
wherein d is the density (g/cm.sup.3) of the copolymer,
the difference between T.sub.1 and the lowest melting point (T.sub.n) among the DSC melting points is given by the following expression (ii)
18.degree. C.<T.sub.1 -T.sub.1 .ltoreq.65.degree. C. (ii),
and the difference between T.sub.1 and the second highest melting point (T.sub.2) is given by the following expression (iii)
0.degree. C.<T.sub.1 -T.sub.2 .ltoreq.20.degree. C. (iii)
provided that when the number of melting points is one (i.e., n=1), only the expression (i) is applicable and the expressions (ii) and (iii) are not applicable,
(H) when n.gtoreq.3 in the characteristic (G) above, the ratio of the amount of heat or crystal fusion (H.sub.1) at the highest melting point T.sub.1 to the total amount of heat of crystal fusion (H.sub.T) is given by the following expression
O<H.sub.1 /H.sub.T .ltoreq.0.40,
(I) it has a crystallinity, measured by an X-ray diffraction method, of from 15 to 70%, and
(J) it has a molecular weight distribution M/M wherein M is the weight average molecular weight of the copolymer and M is the number average molecular weight of the copolymer, measured by gel permeation chromatography of from 2.5 to 10.

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Abstract

Claims4