Back to results
US 4,668,050 AGranted
Method of using liquid crystal device comprising dichroic dye and liquid crystal device
AssigneesCasio Computer Co., Ltd., Showa Chemical Co., Ltd.
InventorsHisashi Aoki, Kaoru Kodera, Tetsuo Okugawa
Life of this patent
Estimating the term…
Abstract
A dichroic dye for use in a liquid crystal comprising at least one compound represented by a formula: ##STR1## The compound includes monoazo, disazo and trisazo compounds. The dye has a high dichroic ratio, a high mole absorptivity and a good compatibility with liquid crystals.
Claims18
A method of controlling the transmission of light by a liquid crystal device, comprising:
- providing a pair of opposed electrodes at least one of which is transparent;
- providing a nematic liquid crystal material filled between said electrodes which has a predetermined absorption characteristic of light, said nematic liquid crystal material comprising at least one nematic liquid crystal and dichroic dye comprising at least one compound having the formula:
- ##STR57## each of R.sup.1 and R.sup.2 is independently hydrogen, halogen, cyano, thiocyano, hydroxyl, mercapto, lower alkyl, fluorinated lower alkyl, lower alkylsulfonyl, fluorinated lower alkylsulfonyl, lower alkoxyl, lower alkylthio, --OR.sup.* --O--R.sup.0, --R.sup.* --OR.sup.0, lower alkylcarbonyl, lower acyloxy, lower alkoxycarbonyl, ##STR58## each R.sup.3 is independently hydrogen, halogen, methyl, ethyl, methoxy, ethoxy, cyano or trifluormethyl;
- each R.sup.4 is independently ##STR59## each of R.sup.5 and R.sup.6 is independently hydrogen, lower alkyl, lower hydroxyalkyl, halogenated lower alkyl, cyano-lower alkyl, ##STR60## each R.sup.7 is independently hydrogen, lower alkyl, ##STR61## each R.sup.8 is independently lower alkyl or ##STR62## each R.sup.9 is independently hydrogen or lower alkyl;
- each R.sup.10 is independently hydrogen, lower alkyl or lower alkoxyl;
- each R.sup.0 is independently lower alkyl;
- each R.sup.* is independently lower alkylene;
- i and j are each 0 or 1
- P is an integer from 1 to 4;
- and
- n is an integer from 1 to 8;
- and
- applying a voltage between said pair of electrodes thereby changing said predetermined absorption characteristic of at least part of said liquid crystal material to control the transmission of light.
10 more elements
A liquid crystal device utilizing a guest-host effect, comprising:
- a pair of opposed electrodes at least one of which is transparent;
- a nematic liquid crystal material filled between said electrodes and comprising at least one nematic liquid crystal and a dichroic dye comprising at least one compound having the generla formula:
- ##STR80## each of R.sup.1 and R.sup.2 is independently hydrogen atom, a halogen atom, cyano group, thiocyano group, hydroxyl group, mercapto group, a lower alkyl group, a fluorinated lower alkyl group, a lower alkylsulfonyl group, a fluorinated lower alkylsulfonyl group, a lower alkoxyl group, a lower alkylthio group, --OR.sup.* --O--R.sup.0 group, --R.sup.* --OR.sup.0 group, a lower alkylcarbonyl group, a lower acyloxy group, a lower alkoxycarbonyl group, ##STR81## each R.sup.3 is independently hydrogen atom, a halogen atom, methyl group, ethyl group, methoxy group, ethoxy group, cyano group or trifluoromethyl group;
- each R.sup.4 is independently ##STR82## each of R.sup.5 and R.sup.6 is independently hydrogen atom, a lower alkyl group, lower hydroxyalkyl group, a halogenated lower alkyl group, a cyano-lower alkyl group, --R.sup.* --COOR.sup.9 group, --R.sup.* --OCOR.sup.9 group, ##STR83## each R.sup.7 is independently hydrogen atom, a lower alkyl group, ##STR84## each R.sup.8 is independently a lower alkyl group or ##STR85## each R.sup.9 is independently hydrogen atom or a lower alkyl group;
- each R.sup.10 is independently hydrogen atom, a lower alkyl group or a lower alkoxyl group;
- each R.sup.0 is independently a lower alkyl group;
- each R.sup.* is independently a lower alkylene group;
- i and j are each 0 or 1;
- p is an integer from 1 to 4;
- n is an integer from 1 to 8;
- and
- means for applying a voltage between said pair of electrodes.
9 more elements
Dependencies are inferred from the claim text.