Method for the preparation of a bicarbonate sorbent in flue gas desulfurization
AssigneeChurch & Dwight Co., Inc.
InventorsJames S. Sarapata, Raymond Shaffery
Life of this patent
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Abstract
A process for the dry carbonation of an alkali metal or ammonium carbonate, utilizing a low carbon dioxide-containing carbonating gas stream, and more particularly, a process for the production of a bicarbonate sorbent useful in the desulfurization of flue gases from the low carbon dioxide-content flue gases themselves.
Claims18
A process for the dry carbonation of an alkali metal or ammonium carbonate selected from the group consisting of soda ash, sodium carbonate monohydrate, sodium sesquicarbonate, trona, the corresponding potassium or ammonium carbonates, and mixtures thereof, consisting essentially of:
- (a) substantially saturating a gas stream containing from 6% to 17% carbon dioxide by volume with water vapor, the moisture content of the gas stream being at least 90% of saturation at the temperature at which the gas stream reacts in step (b);
- and
- (b) reacting solid particles of the carbonate with the gas stream in a turbulent fludiized bed at temperatures of from 100.degree. F. to 200.degree. F., while maintaining a relative humidity of at least 90% in the vapor phase adjacent the particles, to produce an aqueous film on the carbonate particles and provide unhindered transfer of carbon dioxide from the gas stream to the surface of the carbonate particles and unhindered transfer of the heat of reaction from the surface of the carbonate particles to the gas stream, to produce the alkali metal or ammonium bicarbonate per se.
The process of claim:
- 1, wherein the reaction is carried out in step (b) at temperatures of from 100.degree. to 190.degree. F.
A process for desulfurizing hot flue gas containing from 8% to 17% carbon dioxide by volume, consisting essentially of:
- (a) contacting the flue gas with the solid alkali metal or ammonium bicarbonate-containing sorbent made in step (e) to react with sulfur dioxide in the flue gas;
- (b) separating the resulting solid waste and removing it from the gas stream;
- (c) cooling the cleansed gas stream, from which the solid waste has been removed, to temperature of from 100.degree. F. to 200.degree. F.;
- (d) substantially saturating the gas stream with water vapor, the moisture content of the gas stream being at least 90% of saturation at the temperature at which the gas stream reacts in step (e);
- (e) thoroughly mixing the gas stream with an alkali metal or ammonium carbonate selected from the group consisting of soda ash, sodium carbonate monohydrate, sodium sesquicarbonate, trona, the corresponding potassium or ammonium carbonates, and mixtures thereof, in essentially dry, particulate form in a turbulent fluidized bed at temperatures of from 100.degree. F. to 200.degree. F., while maintaining a relative humidity of at least 90% in the vapor phase adjacent the carbonate particles, to form an aqueous film on the particles and provide unhindered transfer of carbon dioxide from the gas stream to the particle surfaces and unhindered transfer of the heat of reaction from the particle surfaces to the gas stream, to thereby produce the bicarbonate of said alkali metal or ammonium bicarbonate;
- and
- (f) supplying the bicarbonate thus produced to step (a) to contact the hot flue gas in an amount sufficient for desulfurization thereof.
Dependencies are inferred from the claim text.