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US 4,659,783 AGranted
Acrylic star polymers containing multifunctional monomers in the core
AssigneeE. I. Du Pont de Nemours and Company
InventorHarry J. Spinelli
Life of this patent
Estimating the term…
Abstract
Large acrylic star polymers, having a low polydispersity of polymer molecular weight and of arm molecular weight and containing multifunctional monomers in the core.
Claims6
A soluble acrylic star polymer comprising
- (a) a crosslinked core consisting essentially of a polymer derived from one or more monomers, each having at least two groups, ##STR33## and (b) attached to the core, at least 5 arms comprising polymer chains derived from one or more monomers, each having one group. ##STR34## in each of which R is the same or different and is H, CH.sub.3, CH.sub.3 CH.sub.2, CN or CO.sub.2 R' and Z' is O or NR', wherein R' is C.sub.1-4 alkyl, wherein:
- at least 50% of the molecules of such star polymers have at least from 5 to 2,000,000 arms, wherein the ratio of the number of arms to the number of difunctional acrylic repeat units in the core is less than or equal to 1:1, and
- (c) wherein the soluble is defined as that nothing separates out from a solution of 1% weight of the star polymer in 99% solvent of toluene, glyme or tetrahydrofuran upon centrifuging at 17,000 rpm for 30 minutes.
Dependencies are inferred from the claim text.