Ethane derivatives
AssigneeMerck Patent GmbH
InventorsJulie E. Fearon, Wendy E. Smith, George W. Gray, David Lacey, Kenneth J. Toyne, Georg Weber
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AssigneeMerck Patent GmbH
InventorsJulie E. Fearon, Wendy E. Smith, George W. Gray, David Lacey, Kenneth J. Toyne, Georg Weber
Estimating the term…
Ethane derivatives of the formula I R.sup.1 --A.sup.1 --CH.sub.2 CH.sub.2 --A.sup.2 --(A.sup.3).sub.n --R.sup.2 I wherein R.sup.1 is H, an alkyl group with 1-12 C atoms, in which one or two non adjacent CH.sub.2 groups can also be replaced by O atoms and/or CO groups and/or --O--CO-- groups and/or --CO--O groups, F, Cl, Br or R.sup.3 --A.sup.4 --Z.sup.1 --, R.sup.2 is --CN or --Z.sup.2 --A.sup.4 --CN, A.sup.1 is --A--, --A--A.sup.5 -- or --A.sup.5 --A--, A.sup.2 is an 1,4-phenylene group which is unsubstituted or substituted by one or two F and/or Cl atoms and/or CH.sub.3 groups and/or CN groups and in which one or two CH groups can also be replaced by N atoms, A is a 1,4-cyclohexylene group, in which one or two non adjacent CH.sub.2 groups can also be replaced by O atoms, or is a 1,3-dithiane-2,5-diyl group or 1,4-bicyclo(2,2,2)-octylene group, A.sup.3, A.sub.4 are each a 1,4-cyclohexylene group, in which one or two non adjacent CH.sub.2 groups can also be replaced by O atoms, or are each a 1,3-dithiane-2,5-diyl group, and A.sup.5 or a 1,4-phenylene group which is unsubstituted or substituted by one or two F and/or Cl atoms and/or CH.sub.3 groups and/or CN groups, and in which one or two CH groups can also be replaced by N atoms, n is 0 or 1, Z.sup.1 is --CO--O--, --O--CO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 or a single bond, Z.sup.2 is --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --O--CO-- or a single bond and R.sup.3 is H or an alkyl group with 1-12 C atoms, in which one or two non adjacent CH.sub.2 groups can also be replaced by O atoms and/or CO groups and/or --CO--O-- groups and/or --O--CO-- groups, with the proviso that (a) if A.sup.2 =A.sup.3 =1,4-phenylene (n=1) and/or if R.sup.1 -A.sup.1 =p-(trans-4-alkylcyclohexyl)-phenyl, at least one of the groups A.sup.2 and/or A.sup.3 is laterally substituted, and (b) if A.sup.1 =A and/or R.sup.1 -A.sup.1 =trans-4-(trans-4-alkylcyclohexyl)-cyclohexyl, n is 1, can be used as components of liquid crystal phases.
In a liquid crystalline phase comprising at least two liquid crystal components, the improvement wherein at least one liquid crystal component is an ethane derivative of the formula
Dependencies are inferred from the claim text.