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US 4,649,219 AGranted
Unsaturated cyclic amido-substituted ether compounds and preparation process thereof
AssigneeMitsui Toatsu Chemicals, Inc.
InventorsHiroshi Itoh, Atsuhiko Nitta, Tomio Tanaka, Hideo Kamio
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Abstract
Disclosed herein are novel unsaturated cyclic amide-substituted ether compounds having a wide range of utility in crosslinking agents, adhesives, paints, raw materials for hygroscopic resins, etc. These compounds are prepared by reacting cyclic halogen-substituted ether compounds with unsaturated amide compounds in the presence of a strong basic substance in an aprotic polar solvent.
Claims4
Unsaturated cyclic amido-substituted ether compound represented by the following general formula (I):
- ##STR36## wherein:
- R.sub.1 is an aromatic ring;
- Z is an alkylene group having 1 or 2 carbon atoms, an alkenylene group having 3 carbon atoms, an oxyalkylene group represented by the general formula --O--C.sub.x H2.sub.x --, wherein x is an integer of 1 or 2, or an aminoalkylene group represented by the general formula:
- ##STR37## wherein y and z are each an integer of 2;
- A is a halogen atom, a hydroxyl group, an oxo group, a cyano group, a nitro group, a mercapto group, a sulfo group, an alkyl group having 1 to 9 carbon atoms, an alkenyl group having 3 carbon atoms, an aminoalkyl group represented by the general formula:
- ##STR38## wherein R' and R" each are an alkyl group having 1 or 2 carbon atoms, or a group represented by the general formula RO-- or RCO--, wherein R is an alkyl group having 1 carbon atom or an aryl group;
- R.sub.2 is a hydrogen atom or a methyl group;
- l is an integer of 0 to 3;
- m is an integer of 4 to 20;
- .alpha. and .beta. each stand for an integer of 0 or 1, with the proviso that .alpha.+.beta.=1.
7 more elements
Dependencies are inferred from the claim text.