Water-soluble dyestuffs containing fibre-reactive groups of the vinylsulfone series and the fluoro-s-triazinyl-amino series

A compound containing one or more sulfonic acid groups, of the formula ##STR116## wherein:

• D is the radical of an organic dye molecule of the formula
• --K.sub.2 -N.dbd.N--A.sub.x --
• or ##STR117## in which A.sub.x is phenylene or phenylene substituted by substituents selected from the group consisting of lower alkyl, lower alkoxy, carboxy, lower alkanoylamino, benzoylamino, sulfo-benzoylamino, phenylamino, sulfophenylamino, carbamoyl, carbamoyl monosubstituted or disubstituted by lower alkyl, phenyl or both, sulfamoyl, sulfamoyl monosubstituted or disubstituted by lower alkyl, phenyl or both, cyano, nitro, chlorine, bromine, fluorine, trifluoromethyl, hydroxy and sulfo, or is a naphthylene unsubstituted or substituted by substituents selected from the group consisting of sulfo, carboxy, methyl, ethyl, methoxy, ethoxy, lower alkanoylamino, benzoylamino, chlorine, hydroxy and nitro,
• K.sub.2 is 2-amino-naphthylene or 2-amino-naphthylene substituted by one or two sulfonic acid groups, or
• K.sub.2 is pyrazol-5-on-4-yl substituted in the 3-position by methyl, carboxy, carbamoyl, lower carbalkoxy or phenyl, and substituted by phenyl or naphthyl bonded in the 1-position, it being possible for this phenyl to be substituted by 1 or 2 sulfo groups or by 1 or 2 substituents selected from the group consisting of lower alkyl, lower alkoxy, chlorine, bromine, nitro, lower alkanoylamino, substituted alkanoylamino, benzoylamino, substituted benzoylamino and carboxy, or by these groups and by 1 or 2 sulfo groups, and for the naphthyl to be substituted by 1, 2 or 3 sulfo groups or by one substituent selected from the group consisting of lower alkyl, lower alkoxy, nitro, lower alkanoylamino, substituted alkanoylamino, benzoylamino, substituted benzoylamino and carboxy, or by one of these groups and one, two or three sulfo groups,
• A.sub.1 is a benzene ring containing no additional substituents or one or two additional substituents (which may be the same or different) selected from the group consisting of lower alkyl, lower alkoxy, carboxy, phenylamino, sulfobenzoylamino, sulfophenylamino, carbamoyl, carbamoyl which is monosubstituted or disubstituted by lower alkyl, phenyl or both, sulfamoyl, sulfamoyl which is monosubstituted or disubstituted by lower alkyl, phenyl or both, cyano, nitro, chlorine, bromine, trifluoromethyl and sulfo, or
• A.sub.1 is a naphthalene ring, or a naphthalene ring substituted by 1, 2 or 3 sulfo groups or by a carboxy, methyl, methoxy, ethoxy, nitro, acetylamino or chlorine or by a carboxy, methyl, methoxy, ethoxy, nitro, acetylamino or chlorine and 1, 2 or 3 sulfo groups,
• K.sub.3 is a naphthalene ring, which is substituted by one or two sulfonic acid groups as additional substituents, the complex-forming oxygen atoms being bonded to A.sub.1 and K.sub.3 in the ortho-positions each relative to the azo group,
• R is hydrogen or alkyl of 1 to 4 C-atoms,
• X is .beta.-sulfatoethyl, and
• Y is a group of the formula ##STR118## in which R.sup.2 is hydrogen, alkyl of from 1 to 4 carbon atoms unsubstituted or substituted by 1 or 2 substituents selected from the group consisting of acetylamino, hydroxy, sulfato, lower alkoxy, sulfo, carboxy, phenyl, naphthyl, phenyl substituted by sulfo, carboxy, methyl, ethyl, methoxy, ethoxy, chlorine, carbamoyl, sulfamoyl or a combination thereof, and naphthyl substituted by chlorine, methyl, methoxy, ethoxy, sulfo, carboxy, or a combination thereof or is cyclohexyl,
• R.sup.3 is hydrogen, alkyl of from 1 to 4 carbon atoms unsubstituted or substituted by 1 or 2 substituents selected from the group of acetylamino, hydroxy, sulfato, lower alkoxy, sulfo, carboxy, phenyl, naphthyl, phenyl substituted by sulfo, carboxy, methyl, ethyl, methoxy, ethoxy, chlorine, carbamoyl, sulfamoyl or a combination thereof, and naphthyl substituted by chlorine, methyl, methoxy, ethoxy, sulfo, carboxy or a combination thereof, or R.sup.3 is phenyl or naphthyl, each unsubstituted or substituted by carboxy, sulfo, lower alkyl, lower alkoxy, hydroxy or chlorine, or R.sup.2 and R.sup.3 together with the nitrogen atom form the morpholino, piperidino or piperazino ring radical.