Polyimido-ester compounds and thermoset resin compositions containing same
AssigneeThe Dow Chemical Company
InventorsRobert E. Hefner, Jr., Douglas L. Hunter
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Abstract
Polyimido-ester compounds having the formula RO-C(O)-R.sub.1 -C(O)-OR are disclosed wherein R is an alkylene N-dicarboximido radical containing cycloolefinic unsaturation and R.sub.1 is the divalent residue of an unsaturated polycarboxylic acid such as fumaric, itaconic, aconitic, mesaconic, or glutaconic acid. These compounds are blended with unsaturated resins such as unsaturated polyester resin or vinyl ester resin, and polymerizable unsaturated monomers such as styrene to provide thermosettable resin compositions which can be cured to provide castings or laminates with improved resistance to thermal aging.
Claims6
A thermosettable resin composition which comprises
- (A) about 5 to about 95 percent by weight based on the total composition weight of at least one resin selected from the group consisting of (a) unsaturated polyester resins, (b) unsaturated polyesteramide resins, (c) dicyclopentadiene modified unsaturated polyester resins, (d) dicyclopentadiene modified unsaturated polyesteramide resins, and (e) vinyl ester resins,
- (B) about 5 to about 95 percent by weight of at least one polymerizable ethylenically unsaturated monomer;
- and
- (C) about 1 to about 70 percent by weight of an imido-ester compound having the formula ##STR5## wherein R is selected fom one of the following groups ##STR6## and R.sub.1 is a divalent radical selected from one of the following groups
- I. --C(X).dbd.CH--
- II. --CH.sub.2 --C(.dbd.Y)--
- III. --CH.dbd.C(Z)--CH.sub.2 --
- wherein
- n=1-6
- m=0-10
- X=hydrogen or methyl
- Y=methylene or isopropylidene
- Z=hydrogen or --COOR
- Q=methylene.
A thermosettable resin composition which comprises
- (A) about 5 to about 95 percent by weight based on the total composition weight of at least one resin selected from the group consisting of (a) unsaturated polyester resins, (b) unsaturated polyesteramide resins, (c) dicyclopentadiene modified unsaturated polyester resins, (d) dicyclopentadiene modified unsaturated polyesteramide resins, and (e) vinyl ester resins,
- (B) about 5 to about 95 percent by weight of at least one polymerizable ethylenically unsaturated monomer;
- and
- (C) about 1 to about 70 percent by weight of an imido-ester compound having the formula ##STR7## where, n=1-6
- m=0--10
- X=hydrogen or methyl
- Q=methylene.
A themosettable resin composition which comprises
- (A) about 5 to about 95 percent by weight based on the total composition weight of at least one resin selected from the group consisting of (a) unsaturated polyester resins, (b) unsaturated polyesteramide resins, (c) dicyclopentadiene modified unsaturated polyester resins, (d) dicyclopentadiene modified unsaturated polyesteramide resins, and (e) vinyl ester resins,
- (B) about 5 to about 95 percent by weight of at least one polymerizable ethylenically unsaturated monomer;
- and
- (C) about 1 to about 70 percent by weight of an imido-ester compound having the formula ##STR8## where Q=methylene.
Dependencies are inferred from the claim text.