Inclusion compounds, intercalation compounds, and solid solutions of colored organic metal compounds which contains a nickel salt or nickel complex of an azobarbituric acid or its tautomer
AssigneeBayer Aktiengesellschaft
InventorsManfred Lorenz, Karl H. Schundehutte
Life of this patent
Estimating the term…
Abstract
New inclusion compound, intercalation compounds or solid solutions which are the nickel salts or nickel complexes of a compound which, in one of its tauteromeric structures, corresponds to the formula ##STR1## which contain at least one other included compound, except for one composition of matter which consists of 45 to 82% by weight of azobarbituric acid/nickel 1:1 complex, 3 to 15% by weight of benzene-sulphonamide, 5 to 20% by weight of nickel acetate and 10 to 20% by weight of water and the use of these materials as pigments are disclosed.
Claims20
An inclusion compound, intercalation compound or solid solution which is a nickel salt or nickel complex, of a compound which, in one of its tauteromeric structures, corresponds to the formula ##STR19## in which the rings designated X and Y are unsubstituted or are substituted by one or two substituents from the group consisting of .dbd.O, .dbd.S, .dbd.NR.sub.7, --NR.sub.6 R.sub.7, --OR.sub.6, --SR.sub.6, --COOR.sub.6, --CN, --CONR.sub.6 R.sub.7, --SO.sub.2 R.sub.8, ##STR20## alkyl, cycloalkyl, aryl and aralkyl, the total number of the endocyclic and exocyclic double bonds for each of the rings X and Y being three,
- R.sub.6 represents hydrogen, alkyl, cycloalkyl, aryl or aralkyl and
- R.sub.7 represents hydrogen, cyano, alkyl, cycloalkyl, aryl, aralkyl, C.sub.1 -C.sub.6 -alkyl-carbonyl, phenylcarbonyl, C.sub.1 -C.sub.6 -alkylsulphonyl, phenylsulphonyl, carbamoyl, carbamoyl which is substituted by C.sub.1 -C.sub.6 -alkyl, phenyl or napthyl, sulphamoyl, sulphamoyl substituted by C.sub.1 -C.sub.6 -alkyl, phenyl or napthyl, guanyl, guanyl substituted by Chd 1-C.sub.6 -alkyl, phenyl or naphthyl,
- wherein the alkyl radicals mentioned are substituted or are unsubstituted by radicals selected from halogen, --OH, --CN, --NH.sub.2 or C.sub.1 -C.sub.6 -alkoxy and the phenyl and naphthyl radicals mentioned are unsubstituted or are substituted by radicals selected from halogen, --OH, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, --NH.sub.2, --NO.sub.2 or --CN, and
- R.sub.8 designates alkyl, cycloalkyl, aryl or aralkyl,
- R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represent hydrogen, alkyl, cycloalkyl, aryl or aralkyl or, as indicated by the broken lines in the formula, form a triazole, imidazole, benzimidazole, pyrimidine or quinazoline ring or a triazole, imidazole, benzimidazole, pyrimidine or quinazoline ring to which further rings are fused,
- R.sub.5 designates --OH, --NR.sub.6 R.sub.7, alkyl, cycloalkyl, aryl, or aralkyl, and
- m, n, o and p each are 1, or in the case where double bonds extend from the ring nitrogen atoms, as indicated by the dotted lines in the formula, each are 0 or 1 containing at least one other included compound, except for one composition of matter which consists of 45 to 82% by weight of azobarbituric acid/nickel 1:1 complex, 3 to 15% by weight of benzene-sulphonamide, 5 to 20% by weight of nickel acetate and 10 to 20% by weight of water.
Dependencies are inferred from the claim text.