Conductive heterocyclic ladder polymers
AssigneeThe United States of America as represented by the Secretary of the Navy
InventorOh-Kil Kim
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Abstract
Phenothiazine Ladder Polymer, PTL (or di-chloro-PTL) was prepared by polydensation of 2,5-diamino-1,4-benzenedithiol with 2,5-dichloro (or 2,3,5,6-tetrachloro)-p-benzoquinone in polyphosphoric acid at 250.degree. C. Phenoxazine Ladder Polymer, POL, was prepared from 2,5-dichloro-p-phenylenediamine and 2,5-dihydroxy-p-benezoquinone under the same conditions as used for PTL synthesis. Di-chloro-POL and other derivatives can be made under a similar condition. These polymers conduct electricity.
Claims14
A polymer of the formula:
- ##STR1## wherein X is a chalcogen;
- wherein Y is hydrogen or halogen;
- and n is the number of repeating units of said polymer.
A polymer of the formula:
- ##STR2## wherein n is the number of repeating units of said polymer.
A polymer of the formula:
- ##STR3## wherein n is the number of repeating units of said polymer.
Dependencies are inferred from the claim text.