Herbicidal N-2-(nitro-5-phenoxy-phenyl)-aminoalkylphosphonic acid and esters
AssigneeCiba-Geigy Corporation
InventorLudwig Maier
Life of this patent
Estimating the term…
Loading patent…
AssigneeCiba-Geigy Corporation
InventorLudwig Maier
Estimating the term…
The present invention relates to (2-nitro-5-aryloxyphenylamino)alkylphosphonic, -alkylphosphinic and -alkylphosphonous acid derivatives of the general formula I ##STR1## wherein X is halogen, CF.sub.3, NO.sub.2, CN, CONH.sub.2 or CSNH.sub.2, Y is nitrogen or --CH.dbd., R is hydrogen, C.sub.1 -C.sub.4 alkyl or aralkyl containing 1 to 4 carbon atoms in the alkyl moiety, R.sub.1 is C.sub.1 -C.sub.4 alkyl, R.sub.2 is C.sub.1 -C.sub.4 alkyl, phenyl or --PO(OR.sub.6).sub.2, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.4 is hydrogen, C.sub.1 -C.sub.4 alkyl or a cation, R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, hydroxyl or an --O-cation group, R.sub.6 is hydrogen or C.sub.1 -C.sub.4 alkyl, m is a value from 0 to 3, n is 0 or 1, p is a value from 0 to 3, and q is 0 or 1, with the proviso that R.sub.1 and R.sub.3 taken together may also be an unsubstituted or substituted C.sub.1 -C.sub.3 alkylene chain and at least one of the symbols n, p and q is a value different from 0. These compounds have useful herbicidal properties.
A (2-nitro-5-aryloxyphenylamino)alkylphosphonic, -alkylphosphonic or -alkylphosphonous acid derivative of the formula ##STR14## wherein X is halogen, CF.sub.3, NO.sub.2, CN, CONH.sub.2 or CSNH.sub.2,
Ethyl N-[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)phenyl]-P-ethylaminomethyl phosphinate according to claim 11.
N-[2-nitro-5-(2-ch loro-4-trifluoromethylphenoxy)-phenyl]-N-methylaminoethylphosphonous acid,
Ethyl N-[2-nitro-5-(2-chloro-4-trifluoromethylphenoxy)-phenyl]-N-methylaminoethy lphosphonous acid halfester.
A compound according to claim 21 of the formula ##STR17## wherein R.sub.4 is hydrogen, methyl or ethyl, and R.sub.5 is methyl or ethyl.
Dependencies are inferred from the claim text.