Heat resistant resin composition
AssigneeHitachi Chemical Company, Ltd.
InventorsHiroshi Nishizawa, Shozo Kasai, Yasunori Okada, Yuichi Osada, Yoshiyuki Mukoyama
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Abstract
A heat resistant resin composition comprising (A) a polyamideimide resin soluble in a cresol type solvent obtained by using a lactam as a reactant, and (B) at least one member selected from the group consisting of a polyester resin, a polyesteramide resin, a polyesterimide resin and a polyesteramideimide resin, preferably heated for conducting a reaction, gives coatings excellent in heat resistance, thermal shock resistance, wear resistance, resistance to hydrolysis, crazing resistance, etc., suitable for enamelled wire.
Claims24
A heat resistant resin coating composition comprising:
- (A) a polyamideimide resin obtained by reacting the following components in a phenolic solvent:
- (a) A polyisocyanate containing an isocyanurate ring in an amount of 0 to 30 equivalent percents based on the total isocyanate equivalent;
- (b) a diisocyanate free of an isocyanurate ring;
- (c) a lactam;
- (d) a tricarboxylic acid anhydride, and
- (e) a compound different from the component (d) and having the formula:
- ##STR3## wherein X and X' are independently a carboxyl group or an acid anydride group;
- Y is a carboxyl group, a hydroxyl group, and acid anhydride group or an amino group;
- n is an integer of 1 or more;
- r is a residue of aromatic aliphatic, alicyclic or heterocyclic group, or a group of the formula:
- --(R.sub.1).sub.m --Z(R.sub.2).sub.l ( 2)
- in which R.sub.1 and R.sub.2 are independently a residue of aromatic, aliphatic, alicyclic or heterocyclic group;
- Z is --CH.sub.2 --, --CO--, --SO.sub.2 -- or --O--;
- and m and l are independently an integer of 1 or 2, in an amount of 0 to 30 equivalent percents based on the total carboxyl equivalent;
- said polyamideimide resin (A) being a branched polyamideimide obtained from components (b), (c) and (d) and at least one of components (a) and (e), and
- (B) at least one member selected from the group consisting of a polyester resin, a polyesteramide resin, a polyesterimide resin and a polyesteramideimide resin;
- the component (B) and the (A) being reacted with each other at a temperature of 120.degree. to 220.degree. C. in the presence of an ester interchange catalyst and said phenolic solvent;
- the amount of the component (A) being 1 to 400 parts by weight based on 100 parts by weight on the component (B).
Dependencies are inferred from the claim text.