Process for producing a dried, stable mixture of alkali metal or alkaline earth metal ferrate (VI) compounds with hydroxides and carbonates
AssigneeOlin Corporation
InventorJerry J. Kaczur
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AssigneeOlin Corporation
InventorJerry J. Kaczur
Estimating the term…
Disclosed is a process for preparing a dried, stable mixture of at least one alkali metal or alkali earth metal ferrate (VI) compound with alkali metal or alkaline earth metal hydroxide and carbonate compounds comprising: (a) vacuum drying a crude ferrate cake which comprises at least one solid alkali metal or alkaline earth metal ferrate (VI) in admixture with a liquid mother liquor comprising of at least one alkali metal or alkaline earth metal hydroxide and water wherein the amount of said hydroxide is from about 20% to about 50% by weight of the mother liquor; said vacuum drying being carried out at a temperature from about 60.degree. C. to about 90.degree. C. for a sufficient amount of time to remove a portion of said water from said mother liquor and thereby increase the hydroxide concentration in the mother liquor to a range from about 55% to about 70% by weight; and (b) further drying said reduced water-content crude ferrate cake at a temperature from about 110.degree. C. to about 160.degree. C. with a heated gas stream for a sufficient amount of time to form a substantially water-free dried ferrate cake; said gas stream containing a sufficient amount of CO.sub.2 to react with a portion of said hydroxide present in said mother liquor and thereby forming a dried, stable mixture of at least one alkali metal or alkaline earth metal ferrate (VI) compound with alkali metal or alkaline earth metal hydroxide and carbonate compounds.
A process for preparing a dried, stable mixture of at least one alkali metal or alkali earth metal ferrate (VI) compound with alkali metal or alkaline earth metal hydroxide and carbonate compounds comprising:
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