Process for the preparation of hydrocarbons
AssigneeShell Oil Company
InventorSwan T. Sie
Life of this patent
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Abstract
Syngas is subjected to Fischer-Tropsch synthesis over a special Co/Zr/SiO.sub.2 catalyst and the C.sub.10 -C.sub.19 fraction of the synthesized product is converted into XHVI lub oil by treating with an organic peroxide.
Claims18
A process for the preparation of a high-viscosity-index lubricating oil, wherein a feed mixture of carbon monoxide and hydrogen is converted into a mixture of hydrocarbons substantially consisting of linear paraffins, by contacting said feed mixture at elevated temperature and pressure with a catalyst comprising 3-60 pbw of cobalt and0.1-100 pbw of at least one other metal selected fom the group consisting of zirconium, titanium and chromium per 100 pbw of silica, alumina or silica-alumina carrier, which catalyst has been prepared by kneading and/or impregnation, that from the mixture of paraffins thus prepared a light fraction is separated which consists substantially of C.sub.10 -C.sub.19 paraffins, and that at least part of said light fraction is converted into a product comprising the desired high-viscosity-index lubricating oil by treating it at an elevated temperature with a peroxide of the general formula R-O-O-R.sup.1, wherein R and R.sup.1 represent alkyl, aryl or acyl moieties.
Dependencies are inferred from the claim text.