Water-soluble fibre-reactive phthalocyanine compounds
AssigneeHoechst Aktiengesellschaft
InventorsPeter Mischke, Hermann Fuchs
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AssigneeHoechst Aktiengesellschaft
InventorsPeter Mischke, Hermann Fuchs
Estimating the term…
Water-soluble fiber-reactive phthalocyanine compounds of the general formula (1) ##STR1## in which Pc denotes the radical of metal-free or metal-containing phthalocyanine, with the sulfonic acid or sulfonamide groups being bonded in the 3-positions of the aromatic rings of the phthalocyanine, R.sub.1 and R.sub.2 each denote a hydrogen atom or an alkyl group of 1-6 carbon atoms and which can be substituted by methoxy, ethoxy, propoxy, C.sub.2 H.sub.5 --O--C.sub.2 H.sub.4 --O--, cyano, acetylamino, carboxyl, HO.sub.3 S--, H.sub.2 O.sub.3 P--, phenyl, methylphenyl, methoxyphenyl, dimethylamino, diethylamino, .beta.-hydroxyethylamino, .beta.-hydroxyethoxy, N-phenylureido, N-alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 ureido or N-cycloalkylureido groups or an allyl, 2-methallyl, crotyl or cycloalkyl group, and R.sub.1 and R.sub.2, together with the nitrogen atom, can represent the radical of a heterocyclic saturated or unsaturated ring, or R.sub.1 and R.sub.2 represent a phenyl radical which can be substituted by methyl, ethyl, methoxy, ethoxy, carboxyl or sulfonic acid groups, R.sub.3 denotes a hydrogen atom or an alkyl group of 1 to 4 carbon atoms and which can be substituted by hydroxyl or carboxyl groups, X represents a hydrogen atom or an alkyl or alkoxy group of 1 to 4 carbon atoms, Y represents the vinyl group or the grouping of the formula --CH.sub.2 --CH.sub.2 --Z in which Z denotes an inorganic or organic radical which can be eliminated under alkaline conditions, a represents a number between 0 and 2, b represents a number between 0 and 2 and c represents a number between 1.7 and 2.6, with the proviso that the sum of a, b and c is at most 4, a process for their preparation, and their use for dyeing wool, silk, polyamide fibers, leather or materials containing hydroxyl groups.
A water-soluble fiber-reactive phthalocyanine compound of the formula (1) ##STR14## in which Pc is a radical of metal-free or metal-containing phthalocyanine, with the sulfonic acid or sulfonamide groups being bonded in the 3-positions of the aromatic rings of the phthalocyanine, in which R.sub.1 and R.sub.2 each is hydrogen or alkyl of from 1-6 carbon atoms or said alkyl substituted by methoxy, ethoxy, propoxy, C.sub.2 H.sub.5 --O--C.sub.2 H.sub.4 --O--, cyano, acetylamino, carboxyl, HO.sub.3 S--, H.sub.2 O.sub.3 P--, phenyl, methylphenyl, methoxyphenyl, dimethylamino, diethylamino, .beta.-hydroxyethylamino, .beta.-hydroxyethoxy, N-phenylureido, N-alkylureido in which the alkyl is from 1-4 carbon atoms or N-cycloalkylureido, or allyl, 2-methallyl, crotyl or cycloalkyl, or R.sub.1 and R.sub.2, together with the nitrogen atom, are a heterocyclic saturated or unsaturated ring, or R.sub.1 and R.sub.2 are phenyl or said phenyl substitued by one or more methyl, ethyl, methoxy, ethoxy, carboxyl or sulfonic acid groups, R.sub.1 and R.sub.2 being in each case identical or different, in which R.sub.3 is hydrogen or alkyl of from 1 to 4 carbon atoms or said alkyl substituted by hydroxyl or carboxyl groups, in which X is hydrogen or alkyl or alkoxy of from 1 to 4 carbon atoms, in which Y is --CH.sub.2 --CH.sub.2 --Z in which Z is --OSO.sub.3 H, --SSO.sub.3 H, --OPO.sub.3 H.sub.2, or --OH, a is a number of from 0 to 2, b is a number of from 0 to 2 and c is a number of from 1.7 to 2.6, with the proviso that the sum of a, b and c is at most 4.
The compound of the formula ##STR15##
The compound of the formula ##STR16##
Dependencies are inferred from the claim text.