Two-component dry-type developer
AssigneeRicoh Company, Ltd.
InventorsSatoru Inoue, Mitsuru Uchida, Kimitoshi Yamaguchi, Mitsuo Aoki, Masami Tomita, Chiaki Uematsu
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Abstract
A two-component dry-type developer which comprises carrier particles coated with silicone resin and toner particles containing as a negative polarity control agent a monoazo metal complex dye. As the monoazo metal complex dye, the following metal complex dye is preferable for use in this two-component dry-type developer: ##STR1## wherein X, Y and Z independently represent hydrogen, halogen, a carboxyl group, a hydroxyl group, a nitro group, a sulfo group or a sulfonamide group; and A.sup.+ represents H.sup.+, K.sup.+, Na.sup.+ or an aliphatic ammonium cation.
Claims14
A two component dry type developer comprising carrier particles coated with a silicone resin and toner particles containing as a negative polarity control agent a monoazo metal complex dye of the formula ##STR14## wherein X, Y and Z independently represent hydrogen, halogen, carboxy, hydroxy, nitro, sulfo or sulfonamide, and A.sup.+ represents H.sup.+, NH.sub.4.sup.+, K.sup.+, Na.sup.+ or an aliphatic ammonium cation.
A two component dry developer for developing an electrostatic latent image, comprising a blend of toner particles and carrier particles, said toner particles being deposited on the surfaces of said carrier particles so as to cover 30% to 90% of the total surface of said carrier particles;
- said carrier particles consisting essentially of core particles having diameters in the range of 20 to 1000 .mu.m selected from the group consisting of particles of sand, cobalt, iron, iron oxide, ferrite, copper, nickel, zinc, aluminum, brass and glass, said core particles being coated with a silicone resin having repeating units of the formula:
- ##STR16## wherein X, Y and Z, each independently represent hydrogen, halogen, hydroxy, methoxy, alkyl having 1-4 carbon atoms, or phenyl, not more than about 30 wt.% of said silicone resin being unhardened;
- and said toner particles consist essentially of a synthetic resin selected from the group consisting of polystyrene, acrylic, polyvinyl chloride, epoxy, alkyd, polyethylene, phenolic, butyral, polyester, xylene and polyamide resins, and 0.1 to 15 wt.%, based on the amount of said resin, of a dye of the formula:
- ##STR17## wherein X, Y and Z independently represent hydrogen, carboxy, hydroxy, nitro, sulfo or sulfonamide, and A.sup.+ represents H.sup.+, NH.sub.4.sup.30, K.sup.+, Na.sup.+ or an aliphatic ammonium cation.
Dependencies are inferred from the claim text.