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US 4,561,998 AGranted
Near-neutral pH detergents containing anionic surfactant, cosurfactant and fatty acid
AssigneeThe Procter & Gamble Company
InventorsJean-Luc H. M. Wertz, Pierre C. E. Goffinet
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Abstract
Detergent compositions, preferably heavy-duty liquids, containing an anionic surfactant, a selected consurfactant and a fatty acid are disclosed. The compositions are formulated to provide an initial pH of from about 6.0 to about 8.5 at a concentration of from about 0.1% to about 2% by weight in water at 20.degree. C. The compositions preferably also contain ethoxylated nonionic surfactants, a detergent builder and enzymes.
Claims13
A detergent composition comprising:
- (a) from about 2% to about 60% by weight of an anionic synthetic surfactant;
- (b) from about 0.25% to about 12% by weight of a cosurfactant selected from the group consisting of:
- (i) quarternary ammonium surfactants having the formula:
- [R.sup.2 (OR.sup.3).sub.y ][R.sup.4 (OR.sup.3).sub.y ].sub.2 R.sup.5 N.sup.+ X.sup.-
- wherein R.sup.2 is an alkyl or alkyl benzyl group having from about 8 to about 18 carbon atoms in the alkyl chain;
- each R.sup.3 is selected from the group consisting of --CH.sub.2 CH.sub.2 --, --CH.sub.2 CH(CH.sub.3)--, --CH.sub.2 CH(CH.sub.2 OH)--, --CH.sub.2 CH.sub.2 CH.sub.2 --, and mixtures thereof;
- each R.sup.4 selected from the group consisting of C.sub.1-4 alkyl, C.sub.1-4 hydroxyalkyl, benzyl, and hydrogen when y is not 0;
- R.sup.5 is the same as R.sup.4 or is an alkyl chain wherein the total number of carbon atoms of R.sup.2 plus R.sup.5 is not more than about 18;
- each y is from 0 to about 10 and the sum of the y values is from 0 to about 15;
- and X is any compatible anion;
- and
- (ii) diquaternary ammonium surfactants having the formula:
- [R.sup.2 (OR.sup.3).sub.y ][R.sup.4 (OR.sup.3).sub.y [.sub.2 N.sup.+ R.sup.3 N.sup.+ R.sup.5 [R.sup.4 (OR.sup.3).sub.y ].sub.2 (X.sup.-).sub.2
- wherein R.sup.2, R.sup.3, R.sup.4, y and x are as defined above;
- (c) from about 5% to about 40% by weight of a fatty acid containing from about 10 to about 22 carbon atoms;
- and
- (d) from about 3% to about 10% by weight of a detergent builder;
- said composition having a molar ratio of the anionic synthetic surfactant to the cosurfactant of at least 1 and formulated to provide an initial pH of from about 6.0 to about 8.5 at a concentration of from about 0.1% to about 2% by weight in water at 20.degree. C.
15 more elements
Dependencies are inferred from the claim text.