Recovery of rhenium
AssigneeGTE Products Corporation
InventorsAlan D. Douglas, Kenneth T. Reilly, John E. Landmesser
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Abstract
In a process for recovering rhenium, a starting material containing tungsten and rhenium is reacted with sodium hydroxide and an oxidizing reactant to form a fused solid. The fused solid is dissolved in water to solubilize the tungsten and rhenium values and then pass through an anion exchange resin to remove the rhenium values and form a solution containing the tungsten values. The resin is stripped to obtain the rhenium values from the resin.
Claims1
A process for recovering rhenium and tungsten values from a rhenium bearing material consisting of about 1 to about 10 percent by weight rhenium metal with a balance consisting essentially of tungsten metal, said process comprising:
- (a) reacting said rhenium bearing material with a mixture of sodium hydroxide and an oxidizing reactant selected from the group consisting of sodium nitrate, sodium nitrite, sodium chlorate, sodium peroxide and mixtures thereof to form a fused solid comprising sodium tungstate and sodium perrhenate, (b) dissolving said fused solid in the water under conditions suitable to form a solution having a pH of from about 10 to about 14 comprising sodium tungstate in an amount from about 50 to about 150 grams per liter based on the weight of tungsten and sodium perrhenate in an amount from about 0.5 to about 15 grams per liter based on the weight of rhenium, contacting said solution with a bed of a strongly basic anion exchange resin to absorb the major portion of the rhenium values and form a rhenium depleted solution comprising substantially all of the tungsten values, (c) stripping the rhenium values from said resin with a nitric acid solution.
Dependencies are inferred from the claim text.