Recording method by use of inks
AssigneeRicoh Company, Ltd.
InventorsTamotsu Aruga, Tadashi Fujii, Kakuji Murakami, Eiichi Akutsu
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Abstract
A recording method by use of an ink is disclosed, in which images are formed by an aqueous ink comprising at least one dye selected from the group consisting of a pyrazolone azo dye, a phthalocyanine sulfonate dye, a xanthene dye and an azo dye on a recording medium containing at least one component selected from the group consisting of a water-soluble metal salt whose metal has an ion valence of 2 or more, an alkyl amine and a quaternary ammonium salt.
Claims14
A recording method which comprises imagewise applying (1) an aqueous ink comprising at least one dye selected from the group consisting of the following dyes (a) through (d) onto (2) a recording medium containing at least one component selected from the group consisting of water soluble metal salts in which the metal has a valence of 2 or more, alkyl amine salts, polyamines and quaternary ammonium salts, whereby to form an image on said recording medium,
- (a) a pyrazolone azo dye of the following formula I ##STR7## where M.sup.+ represents Li.sup.+, Na.sup.+, K.sup.+, Cs.sup.+, NH.sub.4.sup.+ or NR.sub.4.sup.1+ wherein R.sup.1 represents an alkyl group, X.sup.1 represents F, Cl, Br, I or hydrogen, and Y.sup.1 represents hydrogen, an alkyl group or --COO--M.sup.+ ;
- (b) a phthalocyanine sulfonate dye of the following formula II ##STR8## where M.sup.+ is the same as that defined in the formula I, and m m is an integer of 2 to 4;
- (c) a xanthene dye of the following formula III or IV ##STR9## where M represents Li, Na, K, Cs, NH.sub.4 or NR.sub.4.sup.1 wherein R.sup.1 represents an alkyl group, X.sup.2 represents Br, I or Cl, and Y.sup.2 represents Br, I or Cl;
- ##STR10## where M is the same as that in the formula III, and R.sup.2 represents hydrogen or an alkyl group;
- (d) an azo dye of the following formula V or VI ##STR11## where n is an integer of 0 or 1, X.sup.3 represents hydrogen or --NH.sub.2, Y.sup.3 represents hydrogen or --NHR.sup.1 wherein R.sup.1 represents an alkyl group, Z represents hydrogen, --OH or --COOM, and R.sup.3 represents hydrogen, an alkyl group or --SO.sub.3 M wherein M is the same as that defined in formula III;
- ##STR12## wherein X.sup.4 represents hydrogen, --SO.sub.3 M or --COOM in which M is the same as that defined in the formula III.
Dependencies are inferred from the claim text.