A hollow, totally enclosed structure comprising a thin shell totally enclosing an inner void, said thin shell having a lower base and an upper base and a side wall portion, said side wall portion connecting said upper base and said lower base in a substantially continuous fashion, said side wall being substantially impermeable to gas, said upper base being permeable to gas passing therethrough and said lower base being permeable to gas passing therethrough, and contained within at least a major portion of said void, polymeric particles which consist essentially of polymer and a functional fluid, said functional fluid being selected from the group consisting or aromatizers, deodorizers, animal repellents, pheremones, insect repellents, insect attractants, materials capable of diagnosis of physiological and/or psychological aberrations or malfunctions of mammalian species and medicinal products, said functional fluid being capable of being volatilized in the presence of an air stream passing from said lower base to said upper base through said permeable upper base and lower base in a direction substantially parallel to said outer wall, said polymeric particles being produced by means of:
- (a) forming a first flowable mass of poly(epsilon caprolactone) homopolymer having the structure:
- ##STR11## and from 0 up to minor proportion of the structure:
- ##STR12## wherein n is an integer of from about 500 up to about 1,200 with a proviso that the average n in the system varies from about 600 up to about 800 with from about 1% up to about 30% by weight of said functional fluid;
- (b) causing the flowable mass to be formed into an extruded rod using an extruder;
- and
- (c) pelletizing the thus formed extruded rod to form pellets in the solid state;
- said poly(epsilon caprolactone) homopolymer containing a stabilizer.