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US 4,547,606 AGranted
Selective isomerization of di-isopropyl benzene to meta-di-isopropyl benzene
AssigneePCUK Produits Chimiques Ugine Kuhlmann
InventorGeorge A. Olah
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AssigneePCUK Produits Chimiques Ugine Kuhlmann
InventorGeorge A. Olah
Estimating the term…
Resorcinol is prepared in high yield and purity by an improved process through superacid (such as perfluorinated alkanesulfonic acids of one to eighteen carbon atoms or polymeric perfluorinated resinsulfonic acids, such as acidified Nafion-H, catalyzed cleavage rearrangement reaction of meta-bis(2-hydroperoxy-2-propyl)benzene (meta-diisopropylbenzene dihydroperoxide). Part of the process is the preparation of needed meta-diisopropylbenzene in high purity (98-100%) substantially free of other isomers by treating any mixture of diisopropylbenzenes with an excess of anhydrous hydrogen fluoride or a perfluorinated alkanesulfonic acid of one to eighteen carbon atoms and a Lewis acid fluoride, or by alkylating (transalkylating) cumene with a propyl alkylating agent in the aforementioned superacid systems.
A process for producing a substantially pure meta-diisopropyl benzene isomer which comprises reacting a mixture of diisopropyl benzene isomers said mixture being other than a substantially pure meta-diisopropyl benzene isomer with anhydrous hydrogen fluoride in the presence of a Lewis acid fluoride catalyst at a temperature between about -50.degree. and 200.degree. C. to produce said meta-diisopropyl benzene isomer.
A process for preparing a substantially pure meta-diisopropyl benzene isomer which comprises reacting a mixture of diisopropyl benzene isomers, said mixture being other than a substantially pure meta-diisopropyl benzene isomer, with a perfluorinated alkanesulfonic acid of one to eighteen carbon atoms in the presence of a Lewis acid fluoride catalyst at a temperature between about -50.degree. and 200.degree. C. to produce said meta-diisopropyl benzene isomer.
A process for producing a substantially pure meta-diisopropyl benzene isomer from a mixture of various diisopropyl benzene isomers, said mixture being other than a substantially pure meta-diisopropyl benzene isomer, which comprises adding an excess of hydrogen fluoride to said mixture at a temperature range of -50.degree. to 200.degree. C. and subseqently adding a boron trifluoride catalyst to produce said meta-diisopropyl benzene isomer.
Dependencies are inferred from the claim text.