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US 4,544,743 AGranted
Salts of 1,3,5-oxadiazines-2,4,6-triones, 1,3,5-oxadiazines-2,4,6-triones and the preparation thereof
AssigneeSociete Carbochimique
InventorsPierre M. Lambert, Ignacio De Aguirre-Otegui
Life of this patent
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Abstract
This invention relates to new salts of 1,3,5-oxadiazines-2,4,6-triones, to new 1,3,5-oxadiazines-2,4,6-triones and to the preparation thereof.
Claims33
A 1,3,5-oxadiazine-2,4,6-trione salt of the following formula (I):
- ##STR19## in which R represents a monovalent, divalent or trivalent alkyl, alkylene, cycloalkyl or arylalkyl radical containing at most 18 carbon atoms;
- Q represents a mono-, bi- or trivalent metal or a group containing a number n of unsubstituted or mono-, di-, tri-, or tetrasubstituted ammonium, phosphonium or arsonium radicals selected from the group consisting of the radicals of the formulae:
- ##STR20## in which n has the meaning given hereafter, Z represents nitrogen, phosphorus or arsenic, R.sup.I, R.sup.II, R.sup.III and R.sup.IV, which are identical or different, represent hydrogen, an alkyl, an aryl or arylalkyl radical containing 1 to 12 atoms, whereby R.sup.IV may also represent a bivalent alkylene radical containing 4 to 6 carbon atoms and two or three atoms of R.sup.I, R.sup.II, R.sup.III and R.sup.IV may also be joined with one or two nitrogen atoms to form a di-lower alkyl piperidinium group, a lower alkyl pyridinium group or a di-lower alkyltriethylene diammonium group;
- R.sup.V and R.sup.VI, which are identical or different, represent a lower alkylene, lower cycloalkylene or phenylene di-lower alkylene radical;
- p is an integer which is equal to 1 to 3 inclusive, and
- n, represents the oxidation number of the metal or the number of ammonium, phosphonium or arsonium functions present in the Q group and is equal to 1 to 40.
3 more elements
An asymmetrical molecular 1,3,5-oxadiazine-2,4,6-trione having the following formula:
- ##STR21## in which R represents a monovalent, divalent or trivalent alkyl, alkylene, cycloalkyl or arylalkyl radical containing at most 18 carbon atoms;
- p is an integer equal to 1 to 3 inclusive, and
- R' which is different from R, is hydrogen, a halogen atom, a C.sub.1 -C.sub.6 alkyl radical which can be substituted by a chlorine atom, a C.sub.3 -C.sub.4 alkenyl radical which can be substituted by a chlorine atom, a cyclohexyl radical, a benzyl radical which can be substituted by a CF.sub.3, CH.sub.2 Cl or NO.sub.2 group, a C.sub.2 -C.sub.8 acyl radical, a p-arylsulfonyl radical or a lower alkoxy carbonyl methylene radical.
Dependencies are inferred from the claim text.