Polyolefin polymerization process and catalyst
AssigneePhillips Petroleum Company
InventorGil R. Hawley
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Abstract
A catalyst and its method of preparation and use involving reacting a magnesium dihalide, an alkoxytitanium compound and water, followed by reaction with an organoaluminum compound and then with a halide ion exchanging source.
Claims14
A process for the polymerization of alpha olefins comprising contacting said alpha olefins under polymerization conditions with a catalyst prepared by reacting an alkoxytitanium compound, a phenol, and a small quantity of water in a hydrocarbon liquid, then reacting the resulting solution with a magnesium dihalide having less than 1.5 moles of water per mole of magnesium dihalide to form a first catalyst component solution, then reacting that solution with an organoaluminum halide to form a solid product, and then reacting said solid product with a halogenating agent comprising a titanium halide, wherein the amount of water employed in forming said first catalyst component solution is such that the catalyst is more active than if no water were employed.
Dependencies are inferred from the claim text.