Silver halide photographic emulsion
AssigneeFuji Photo Film Co., Ltd.
InventorsYuji Mihara, Satoshi Nagaoka, Masaki Okazaki
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Abstract
A silver halide photographic emulsion is disclosed which includes a sensitizing dye represented by general formula (I) and a compound represented by general formula (II): ##STR1## The substituents within the general formulae are defined within the specification. The emulsion can be used to prepare a photographic material which has high green-sensitivity which is obtained without expanding the wavelength region of spectral sensitivity in the green sensitive region. Further, the resulting material has these improved results and does not show substantial change of its photographic properties such as sensitivity and amount of fogging during storage.
Claims17
A silver halide photographic emulsion, comprising:
- a binder having dispersed therein:
- silver halide grains;
- a sensitizing dye represented by general formula (I);
- and
- a compound represented by general formula (II):
- ##STR11## wherein:
- W.sub.1, W.sub.2, W.sub.3 and W.sub.4, which may be the same or different, each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group, a trifluromethyl group or a hydroxy group;
- R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an unsubstituted or substituted alkyl group;
- an unsubstituted or substituted cycloalkyl group or an unsubstituted or substituted alkenyl group, provided that at least one of R.sub.3 and R.sub.4 represents a substituted alkyl, cycloalkyl or alkenyl group containing a sulfo group or a carboxy group;
- X represents an acid anion;
- n represents 1 or 2;
- ##STR12## wherein:
- R.sub.5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxycarbonyl group, an acyloxy group, an alkoxy group, an amino group, a substituted amino group, an acylamido group or a carbamoyl group;
- Y represents an alkylene group, an arylene group, an aralkylene group, --COO-- or --COO--Y.sub.1 --OCO-- where Y.sub.1 represents an alkylene group, an arylene group or an aralkylene group;
- X.sub.1 represents an anion;
- m.sub.1 and m.sub.2 each represents an integer of from 1 to 19.
Dependencies are inferred from the claim text.