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US 4,544,553 AGranted
Pesticidal phosphoroamido (di) thioates
AssigneeRohm and Haas Company
InventorsJoel R. Smolanoff, J. Michael Fitzpatrick, Janet Ollinger
Life of this patent
Estimating the term…
Abstract
This invention relates to phosphoroamidothioate and phosphorcamidodithioate compounds, to compositions thereof which are useful as pesticides. For example, as arthropodicides (that is, insecticides and acaricides), nematocides, and fungicides, and to a method of controlling pests, such as insects, acarids, nematodes, and fungi. The compounds of the invention are effective against soil insects, especially the corn rootworm, when applied by soil application techniques and are also effective when applied to agricultural plants and other plants by foliar application techniques.
Claims17
A compound having the formula:
- ##STR15## wherein:
- R.sup.1 is unsubstituted or substituted (C.sub.1 -C.sub.4) alkyl wherein the substituent can be one (C.sub.1 -C.sub.4)alkoxy or from one to four of the same or different bromo, chloro or fluoro groups;
- (C.sub.3 -C.sub.6) alkenyl;
- (C.sub.3 -C.sub.6) alkynyl;
- unsubstituted or substituted phenyl wherein the substituent can be from one to three of the same or different alkyl, haloalkyl, halo, alkoxy, alkylthio, cyano, nitro, amino, or mono- or di-alkylamino, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- or unsubstituted or substituted phenyl (C.sub.1 -C.sub.3) alkyl wherein the substituent on the phenyl ring can be from one to three of the same or different alkyl, haloalkyl containing one to three of the same or different halo, alkoxy, alkylthio, cyano, nitro, amino, or mono- and di-alkylamino groups, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- R.sup.2 is unsubstituted straight or branched chain (C.sub.3 -C.sub.5) alkyl or substituted (C.sub.2 -C.sub.5) alkyl wherein the substituent can be from one to three of the same or different alkyl, halo, alkoxy, alkylthio, cyano, nitro, amino, or mono- or di-alkylamino, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms, (C.sub.3 -C.sub.6) alkenyl;
- (C.sub.3 -C.sub.6) alkynyl;
- (C.sub.3 -C.sub.6) cycloaliphatic or heterocycloaliphatic;
- unsubstituted or substituted phenyl wherein the substituent can be from one to three of the same or different alkyl, haloalkyl containing one to three of the same or different halo, alkoxy, alkylthio, cyano, nitro, amino, or mono- or di-alkylamino, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- or unsubstituted or substituted phenyl (C.sub.1 -C.sub.3) alkyl wherein the substituent on the phenyl ring can be from one to three of the same or different alkyl, haloalkyl containing one to three of the same or different halo, alkoxy, alkylthio, cyano, nitro, amino, or mono- and di-alkylamino groups, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- R.sup.3 is hydrogen, methyl, trifluoromethyl, carbo(C.sub.1 -C.sub.4)alkoxy, or thiocarbo(C.sub.1 -C.sub.4)alkoxy;
- R.sup.4 is unsubstituted or substituted (C.sub.1 -C.sub.7) alkyl wherein the substituent can be one to three of the same or different carbo(C.sub.1 -C.sub.4)alkoxy, halo, alkoxy, benzoyl, alkylthio, cyano, nitro, unsubstituted or substituted phenoxy or phenylthio wherein the substituent can be from one to three of the same or different alkyl, alkoxy, halo, cyano, nitro, or alkylthio, or amino or mono- or di-alkylamino, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- unsubstituted or substituted (C.sub.3 -C.sub.6) alkenyl wherein the substituent can be from one to three of the same or different phenyl, alkyl, carbo(C.sub.1 -C.sub.4)alkoxy, bromo, chloro or fluoro groups;
- (C.sub.3 -C.sub.6) alkynyl;
- unsubstituted or substituted phenyl wherein the substituent can be from one to five of the same or different halo or from one to three of the same or different alkyl, haloalkyl containing one to three of the same or different halo, alkoxy, alkylthio, cyano, nitro, amino, or mono- or di-alkylamino, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- or unsubstituted or substituted phenyl, or naphthyl, (C.sub.1 -C.sub.3) alkyl wherein the substituent is on the phenyl ring and wherein the substituent can be from one to five of the same or different halo or from one to three of the same or different alkyl, haloalkyl containing one to three of the same or different halo, alkoxy, alkylthio, benzoyloxy, methylenedioxy, cyano, nitro, amino, or mono- or di-alkylamino groups, wherein the alkyl moiety is straight or branched chain and contains from one to three carbon atoms;
- Y and Z are independently O or S.
15 more elements
Dependencies are inferred from the claim text.