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US 4,543,952 AGranted
Flexible copolymers of p-(hydroxyalkoxy)benozic acid and pliant surgical products, particularly monofilament surgical sutures, therefrom
AssigneeEthicon, Inc.
InventorsShalaby W. Shalaby, Donald F. Koelmel
Life of this patent
Estimating the term…
Abstract
Novel flexible polyesters comprising copolymers made from an alkylene oxybenzoate and one of the following sequences: (1) an alkylene, 2-alkenyl- (or alkyl-) succinate; (2) an alkylene dimerate (from the dimer of a long chain unsaturated fatty acid), and pliant surgical products, particularly monofilament surgical sutures, therefrom.
Claims13
A surgical filament comprising a random copolymer of the formula:
- ##STR5## wherein m represents a number having an average value of from 2 to 6, wherein x and y represent numbers having average values such that the units represented by A comprise from about 1 to about 50 weight percent of the copolymer, the remainder comprising the alkyleneoxy benzoate units, and wherein the A units represent at least one of the following units (1) or (2):
- --CO--CHR--CH.sub.2 --CO--O--CH.sub.2)--O]-- (1)
- wherein n represents a number having an average value of from 2 to 12, and wherein R represents alkyl or 2-alkenyl of from 8 to 24 carbon atoms;
- or
- --CO--DA--CO--O(CH.sub.2)--O-- (2)
- wherein DA represents the residue after removal of the carboxyl groups of a dimer acid of long chain unsaturated fatty acid, said residue having an approximate formula of C.sub.34 H.sub.66, and wherein n represents a number having an average value of 2 to 12;
- wherein said filament is characterized by the following physical properties:
- Knot strength greater than about 25.times.10.sup.3 psi
- Tensile strength greater than about 45.times.10.sup.3 psi
- Young's Modulus less than about 250.times.10.sup.3 psi.
7 more elements
A solid surgical aid molded or machined from a copolymer of the formula:
- ##STR6## wherein m represents a number having an average value of from 2 to 6, wherein x and y represent numbers having average values such that the units represented by A comprise from a about 1 to about 50 weight percent of the copolymer, the remainder comprising the alkyleneoxy benzoate units, and wherein the A units represent at least one of the following units (1) or (2):
- --CO--CHR--CH.sub.2 --CO--O--CH.sub.2)--O]-- (1)
- wherein n represents a number having an average value of from 2 to 12, and wherein R represents alkyl or 2-alkenyl of from 8 to 24 carbon atoms;
- or
- --CO--DA--CO--O(CH.sub.2)--O-- (2)
- wherein DA represents the residue after removal of the carboxyl groups of a dimer acid of long chain unsaturated fatty acid, said residue having an approximate formula of C.sub.34 H.sub.66, and wherein n represents a number having an average value of 2 to 12.
3 more elements
Dependencies are inferred from the claim text.