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US 4,542,244 AGranted
Oxabicycloalkane herbicides
AssigneeShell Oil Company
InventorsGeorge B. Payne, Samuel B. Soloway, James E. Powell, Steven A. Roman, Willy D. Kollmeyer
Life of this patent
Estimating the term…
Abstract
Certain substituted 3-cyclohexene-1-ol are intermediates to herbicides and plant growth.
Claims10
A compound of the formula Ig ##STR44## wherein R is a hydrogen atom;
- or a straight-chain alkyl group containing from 1 to 6 carbon atoms;
- R.sup.1 is a hydrogen atom;
- an alkyl group containing from 1 to 6 carbon atoms;
- an alkyl group containing from 1 to 6 carbon atoms substituted by 1 to 3 halogen atoms, each having an atomic number of from 9 to 35, inclusive, a hydroxy group, a cyano group or an alkoxy group containing from 1 to 4 carbon atoms, a C.sub.1-6 alkylthio group, a C.sub.6-10 arylthio group, a C.sub.7-11 aralkylthio group, an azido group, a C.sub.1-6 alkoxycarbonyl group, a hydroxycarbonyl group, a phosphoryl group, a phosphoryloxy group, a carbamoyl group or a thiocarbamoyl group substituted by hydrogen or 1 or 2 alkyl groups containing from 1 to 6 carbon atoms;
- an aryl or aralkyl group, each containing from 6 to 10 carbon atoms, and 1 or 2 carbons in the alkyl portion;
- an aryl or aralkyl group containing from 6 to 10 carbon atoms, and 1 to 2 carbons in the alkyl portion, ring-substituted by one or more substituents independently selected from a halogen atom, each having an atomic number of from 9 to 35, inclusive, an alkyl or alkoxy group containing from 1 to 2 carbon atoms, or an alkyl or alkoxy group containing from 1 to 2 carbon atoms substituted by one or more halogen atoms, each having an atomic number of from 9 or 17;
- R.sup.1 is a group --CO.sub.2 R.sup.6 or --CON(R.sup.6).sub.2 in which R.sup.6 is a hydrogen atom, or an alkyl group containing from 1 to 6 carbon atoms;
- each R.sup.3 is independently selected from a hydrogen atom;
- a chlorine atom;
- a bromine atom;
- an alkyl group containing from 1 to 4 carbon atoms;
- an alkyl group containing from 1 to 4 carbon atoms substituted by 1 to 3 halogen atoms, each having an atomic number of from 9 to 35, inclusive;
- or two of R.sup.3 when located on adjacent carbon atoms together form an epoxide ring or a carbon-carbon bond;
- R.sup.4 is a hydrogen atom;
- an alkyl group containing from 1 to 4 carbon atoms;
- or an alkyl group containing from 1 to 4 carbon atoms substituted by 1 to 3 halogen atoms having an atomic number of from 9 to 35, inclusive;
- each R.sup.5 is independently selected from a hydrogen atom;
- an alkyl group containing from 1 to 4 carbon atoms;
- an alkyl group containing 1 to 4 carbon atoms substituted by 1 to 3 halogen atoms having an atomic number of from 9 to 35, inclusive;
- or a hydroxy group;
- and stereoisomeric forms or mixtures thereof, with the proviso that R and R.sup.1 are not both hydrogen atoms and when R is methyl R.sup.3, R.sup.4 and R.sup.5 all are hydrogen atoms, then R.sup.1 is other than isopropyl.
18 more elements
Dependencies are inferred from the claim text.