Insecticidal cyclopropane carboxylic acid derivatives with 3-unsaturated-side chain
AssigneeRoussel Uclaf
InventorsJacques Martel, Jean Tessier, Andre Teche
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Abstract
Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## The double bond having Z or E geometry and having insecticidal and nematocidal activity as well as plant and animal acaricidal activity.
Claims25
A compound selected from the group consisting of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR58## wherein A' is selected from the group consisting of (1) ##STR59## wherein B is selected from the group consisting of --CH.sub.2 --, ##STR60## and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3, --C.tbd.N and --C.tbd.CH, D is selected from the group consisting of hydrogen and fluorine, n is an integer from 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR61## wherein R.sub.13 is selected from the group consisting of hydrogen and --CN, ##STR62## wherein R.sub.14 is selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and 4 ##STR63## wherein R.sub.14 has the above definition, p is 1, R.sub.17 is hydrogen, B' is selected from the group consisting of --O-- and --S--, R is selected from the group consisting of --(CH.sub.2).sub.n --C--Hal.sub.3, --(CH.sub.2).sub.npl --CHHal.sub.2, --(CH.sub.2).sub.n --CH.sub.2 --Hal,--C--(CHal.sub.3).sub.3, ##STR64## Hal is a halogen and n is an integer from 1 to 8, the double bond having Z or E geometry.
Dependencies are inferred from the claim text.