Process for the recovery and recycle of effluent gas from the regeneration of particulate matter with oxygen and carbon dioxide
AssigneeAir Products and Chemicals, Inc.
InventorWilliam P. Hegarty
Life of this patent
Estimating the term…
Abstract
A unique process arrangement is disclosed wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a mixture of pure oxygen diluted with carbon dioxide is processed to provide a carbon dioxide-rich recycle gas stream to be mixed with oxygen as regenerator feed gas; and a net combustion product stream from which are recovered SO.sub.x and NO.sub.x to eliminate atmospheric emissions, and a pure CO.sub.2 product for export. An alternate embodiment also produces hydrogen or synthesis gas for export.
Claims9
A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a combustion zone with a mixture of commercially pure oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream, comprising the steps of:
- (a) introducing the effluent flue gas into a carbon monoxide combustion stage wherein essentially all of the carbon monoxide content of the gas is converted to carbon dioxide by combustion with oxygen gas;
- (b) reducing the temperature of the resulting combusted effluent gas of step (a) by indirect heat exchange in a waste heat boiler and recovering the waste heat from said gas;
- (c) direct cooling and quenching the effluent gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant adsorption of sulfur dioxide from the gas;
- (d) compressing the effluent gas to approximately the inlet pressure of the combustion zone;
- (e) separating the effluent gas into a carbon dioxide-rich recycle gas stream which constitutes 61-80 percent of the effluent stream and a remaining net gas stream which comprises the balance of the effluent stream;
- (f) recycling the carbon dioxide-rich recycle gas stream to the combustion zone as the diluent for oxygen fed to the zone for combustion;
- (g) compressing the net gas stream to a further elevated pressure;
- (h) aftercooling the compressed net gas stream with the attendant removal of condensed water;
- (i) drying the net gas stream to remove essentially any residual moisture, and
- (j) distilling the net gas stream to recover a gaseous overhead stream of oxygen and carbon dioxide, a liquid carbon dioxide stream formed by the condensed reflux of the distillation and a liquid bottom stream containing oxides of sulfur and nitrogen.
A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by complete combustion in a combustion zone, wherein essentially no residual carbon monoxide exists, with a mixture of oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream comprising the steps of:
- (a) reducing the temperature of the resulting combusted effluent gas by indirect heat exchange in a waste heat boiler and recovering the waste heat from said gas;
- (b) direct cooling and quenching the effluent gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant absorption of sulfur dioxide from the gas;
- (c) compressing the effluent gas to approximately the inlet pressure of the combustion zone;
- (d) separating the effluent gas into a carbon dioxide-rich recycle gas stream which constitutes 61-80 percent of the effluent stream and a remaining net gas stream which comprises the balance of the effluent stream;
- (e) recycling the carbon dioxide-rich recycle gas stream to the combustion zone as the diluent for oxygen fed to the zone for combustion;
- (f) compressing the net gas stream to a further elevated pressure;
- (g) aftercooling the compressed net gas stream with the attendant removal of condensed water;
- (h) drying the net gas stream to remove essentially any residual moisture, and
- (i) distilling the net gas stream to recover a gaseous overhead stream of oxygen and carbon dioxide, a liquid carbon dioxide stream produced from the condensed reflux of the distillation and a liquid bottom stream containing oxides of sulfur and nitrogen.
A process wherein the effluent flue gas from the removal of hydrocarbonaceous coke from particulate matter by combustion in a combustion zone with a mixture of oxygen diluted to a concentration of 24-30 mole percent with carbon dioxide is treated to provide a carbon dioxide-rich recycle gas stream and a carbon-monoxide-rich stream for further processing, comprising the steps of:
- (a) reducing the temperature of the effluent flue gas from the combustion zone to 150.degree.-425.degree. C. and recovering waste heat;
- (b) passing the effluent flue gas over a deoxygenation and reducing catalyst to eliminate oxygen and reduce SO.sub.X to H.sub.2 S and NO.sub.X to N.sub.2 ;
- (c) further reducing the temperature of the effluent flue gas recovering waste heat;
- (d) quenching the effluent flue gas by the introduction of a water stream into the gas with the attendant condensation of water of combustion and the entrainment of particulates into the water stream with subsequent removal of the stream from the gas and without significant absorption of sulfur from the gas;
- (e) compressing the effluent flue gas to a pressure in the range of 10 to 20 atm. and drying the pressurized stream;
- (f) separating a carbon dioxide-rich recycle stream and a net combustion product gas in a low temperature phase separation of the effluent flue gas;
- (g) recycling the carbon dioxide-rich recycle stream to the combustion zone as the diluent for oxygen fed to the zone for combustion;
- (h) compressing the net combustion product gas to an elevated pressure;
- (i) converting at least a part of the carbon monoxide content of the net combustion product stream by the shift reaction to reduce the carbon monoxide content of the stream and produce hydrogen and additional carbon dioxide, and
- (j) separating the stream into a carbon dioxide stream, a hydrogen stream and a hydrogen sulfide stream by a solvent sorption system.
Dependencies are inferred from the claim text.