Process for preparing Zn-Fe base alloy electroplated steel strips
AssigneeKawasaki Steel Corporation
InventorsKazuaki Kyono, Shigeo Kurokawa, Hajime Kimura, Toshio Irie, Takahisa Yoshihara, Akira Matsuda
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AssigneeKawasaki Steel Corporation
InventorsKazuaki Kyono, Shigeo Kurokawa, Hajime Kimura, Toshio Irie, Takahisa Yoshihara, Akira Matsuda
Estimating the term…
Steel strips are electroplated with a Zn-Fe base alloy containing 10 to 30% by weight of iron in a chloride bath which contains zinc and ferrous chlorides to give a total concentration of zinc and ferrous ions of from 1.0 mol/l to the solubility limit with a weight ratio of Fe.sup.2+ /Zn.sup.2+ between 0.10 and 0.35, and chloride ions in a total concentration of at least 6.0 mol/l under electrolytic conditions: pH 1.0-6.0, current density 80-200 A/dm.sup.2, and relative flow velocity 30-200 m/min. The bath may further contain a polycarboxylic acid such as citric acid and a Zn-Fe-P alloy plating may be deposited when the bath further contains hypophosphorous acid.
A process for preparing a Zn-Fe base alloy electroplated steel strip by electroplating a steel strip with a Zn-Fe base alloy containing 10 to 30% by weight of iron to form a Zn-Fe base alloy plating having improved surface properties, characterized in that the electroplating is conducted in a chloride bath which contains zinc and ferrous ions in a total concentration of from 1.0 mol/l to the solubility limit with a weight ratio of Fe.sup.2+ /Zn.sup.2+ between 0.10 and 0.35, and chloride ions in a total concentration of at least 6.0 mol/l under electrolytic conditions:
A process for preparing a Zn-Fe base alloy electroplated steel strip by electroplating a steel strip with a Zn-Fe base alloy containing 10 to 30% by weight of iron to form a Zn-Fe base alloy plating having improved surface properties, characterized in that the electroplating is conducted in a chloride bath which contains zinc and ferrous ions in a total concentration of from 1.0 mol/l to the solubility limit with a weight ratio of Fe.sup.2+ /Zn.sup.2+ between 0.10 and 0.35, chloride ions in a total concentration of at least 6.0 mol/l, and 0.0005 to 0.05 mol/l of hypophosphorous acid or a salt thereof under electrolytic conditions:
Dependencies are inferred from the claim text.