Protected ethynylated phenols
AssigneeThe United States of America as represented by the Secretary of the Air Force
InventorsJ. Shield Wallace, Fred E. Arnold
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Abstract
An acetylenic end-capping agent of the general formula ##STR1## wherein R.sup.1 and R.sup.2 can be the same or different and are selected from the group consisting of hydrogen, C11 to C4 alkyl, phenyl and substituted phenyl, and wherein R.sup.1 and R.sup.2 together with the carbon atom to which they are attached form a saturated 5- or 6-membered ring. This end-capping agent is substantially free of Pd and Cu. Also provided is a method for producing this end-capping agent and a method for producing acetylene terminated compounds.
Claims5
A method for preparing a compound of the formula ##STR14## wherein R.sup.1 and R.sup.2 are the same or different and are selected from the group consisting of hydrogen, C1 to C4 alkyl, phenyl and substituted phenyl, and wherein R.sup.1 and R.sup.2 together with the carbon atom to which they are attached form a saturated 5- or 6-membered ring, which comprises the steps of reacting a halophenol of the formula ##STR15## wherein X is --F, --Cl or --Br, with an acetylenic compound of the formula ##STR16## wherein R.sup.1 and R.sup.2 are as defined above, in the presence of an amine solvent, a catalytic amount of a palladium complex catalyst system and a promoting amount of a cuprous salt promoter under reaction conditions, and recovering the resulting protected ethynylated phenol compound wherein said reaction conditions include a temperature of about 20.degree. to 200.degree. C., a reaction pressure of atmospheric up to about 250 psig, and a reaction time of about 1 to 150 hours.
A method for producing an acetylene terminated compound which comprises reacting, under reaction conditions, a halogen-terminated compound selected from the group consisting of sulfones, polyimide oligomers, polyarylene oxide oligomers and poly(2,6-benzothiazole) oligomers with a compound of the formula ##STR17## wherein R.sup.1 and R.sup.2 are the same or different and are selected from the group consisting of hydrogen, C1 to C4 alkyl, phenyl, and substituted phenyl, and wherein R.sup.1 and R.sup.2 together with the carbon atom to which they are attached form a saturated 5- or 6-membered ring, to form an intermediate product, and cleaving said intermediate product with a suitable base to form said acetylene-terminated compound wherein said reaction conditions include a temperature of about 50.degree. to 150.degree. C., a reaction pressure of atmospheric up to about 250 psig, and a reaction time of about 1 to 50 hours.
Dependencies are inferred from the claim text.